Organocatalytic asymmetric [alpha]-benzoyloxylation of [alpha]-branched aldehydes and enals: a useful approach to oxygenated quaternary stereocenters

Direct asymmetric [alpha]-benzoyloxylation of [alpha]-branched aldehydes and [alpha]-branched enals via enamine and dienamine catalysis was used to construct quaternary oxygenated stereocenters with good yields and moderate to good enantioselectivity. This method uses an inexpensive and readily avai...

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Veröffentlicht in:	Tetrahedron 2012-09, Vol.68 (37), p.7568-7574
Hauptverfasser:	Demoulin, Nicolas, Lifchits, Olga, List, Benjamin
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Amines Asymmetry Benzoyl peroxide Catalysis Derivatives Oxygenated Tetrahedrons
Online-Zugang:	Volltext
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