Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis(N-heterocyclic thione) (SCS-NHT) Pd pincer complex

Treatment of 1,3-bis(3'-butylimidazolyl-1'-yl)benzene diiodide with elemental sulfur in the presence of a base produced a bis(N-heterocyclic thione) (NHT) pincer ligand precursor. Its reaction with PdCl2(CH3CN)2 produced chloro[1,3-bis(3'-butylimidazole-2'-thione-κ-S)benzene-κ-C]...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2015-08, Vol.44 (32), p.14475-14482
Hauptverfasser:	Tyson, Ginger E, Tokmic, Kenan, Oian, Casey S, Rabinovich, Daniel, Valle, Henry U, Hollis, T Keith, Kelly, John T, Cuellar, Kristina A, McNamara, Louis E, Hammer, Nathan I, Webster, Charles Edwin, Oliver, Allen G, Zhang, Min
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalytic activity Chemical reactions Ligands Molecular structure Palladium Precursors Synthesis X-rays
Online-Zugang:	Volltext
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