Photocontrolled Reversible Conversion of Nanotube and Nanoparticle Mediated by β-Cyclodextrin Dimers
A photochemically interconvertible supramolecular nanotube–nanoparticle system was constructed through secondary assembling of self‐aggregates of amphiphilic porphyrin derivatives mediated by trans‐ and cis‐azobenzene‐bridged bis(permethyl‐β‐cyclodextrin). Significantly, these nanotubes and nanopart...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2015-08, Vol.54 (32), p.9376-9380 |
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| creator | Sun, He-Lue Chen, Yong Zhao, Jin Liu, Yu |
| description | A photochemically interconvertible supramolecular nanotube–nanoparticle system was constructed through secondary assembling of self‐aggregates of amphiphilic porphyrin derivatives mediated by trans‐ and cis‐azobenzene‐bridged bis(permethyl‐β‐cyclodextrin). Significantly, these nanotubes and nanoparticles were able to interconvert upon irradiation at different wavelengths, and this photocontrolled morphological conversion is reversible and recyclable for tens of times, which will provide a feasible and convenient way to construct the ordered nanostructure with various morphologies that can be smartly controlled by the environmentally benign external stimulus.
Photodriven interconversion: A photoswitchable supramolecular nanotube–nanoparticle system was constructed through secondary assembly of self‐aggregates of amphiphilic porphyrin derivatives (see picture). These nanoassemblies repeatedly interconvert upon irradiation at 365 and 450 nm. |
| doi_str_mv | 10.1002/anie.201503614 |
| format | Article |
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Photodriven interconversion: A photoswitchable supramolecular nanotube–nanoparticle system was constructed through secondary assembly of self‐aggregates of amphiphilic porphyrin derivatives (see picture). These nanoassemblies repeatedly interconvert upon irradiation at 365 and 450 nm.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201503614</identifier><identifier>PMID: 26089230</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Assembly ; Azo Compounds - chemistry ; beta-Cyclodextrins - chemistry ; Circular Dichroism ; Construction ; Conversion ; Derivatives ; Dimerization ; Irradiation ; Isomerism ; Light ; Nanoparticles ; Nanoparticles - chemistry ; Nanoparticles - ultrastructure ; Nanostructure ; Nanotubes - chemistry ; photochemistry ; photocontrol ; Porphyrins ; self-assembly ; Spectrometry, Fluorescence ; supramolecular chemistry</subject><ispartof>Angewandte Chemie International Edition, 2015-08, Vol.54 (32), p.9376-9380</ispartof><rights>2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4014-eb69ef095d24884769b65b4fbfb8fc7c7f09dafa12b3ed523ea350aaa8b5afdb3</citedby><cites>FETCH-LOGICAL-c4014-eb69ef095d24884769b65b4fbfb8fc7c7f09dafa12b3ed523ea350aaa8b5afdb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201503614$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201503614$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,782,786,1419,27931,27932,45581,45582</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26089230$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sun, He-Lue</creatorcontrib><creatorcontrib>Chen, Yong</creatorcontrib><creatorcontrib>Zhao, Jin</creatorcontrib><creatorcontrib>Liu, Yu</creatorcontrib><title>Photocontrolled Reversible Conversion of Nanotube and Nanoparticle Mediated by β-Cyclodextrin Dimers</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>A photochemically interconvertible supramolecular nanotube–nanoparticle system was constructed through secondary assembling of self‐aggregates of amphiphilic porphyrin derivatives mediated by trans‐ and cis‐azobenzene‐bridged bis(permethyl‐β‐cyclodextrin). Significantly, these nanotubes and nanoparticles were able to interconvert upon irradiation at different wavelengths, and this photocontrolled morphological conversion is reversible and recyclable for tens of times, which will provide a feasible and convenient way to construct the ordered nanostructure with various morphologies that can be smartly controlled by the environmentally benign external stimulus.
Photodriven interconversion: A photoswitchable supramolecular nanotube–nanoparticle system was constructed through secondary assembly of self‐aggregates of amphiphilic porphyrin derivatives (see picture). These nanoassemblies repeatedly interconvert upon irradiation at 365 and 450 nm.</description><subject>Assembly</subject><subject>Azo Compounds - chemistry</subject><subject>beta-Cyclodextrins - chemistry</subject><subject>Circular Dichroism</subject><subject>Construction</subject><subject>Conversion</subject><subject>Derivatives</subject><subject>Dimerization</subject><subject>Irradiation</subject><subject>Isomerism</subject><subject>Light</subject><subject>Nanoparticles</subject><subject>Nanoparticles - chemistry</subject><subject>Nanoparticles - ultrastructure</subject><subject>Nanostructure</subject><subject>Nanotubes - chemistry</subject><subject>photochemistry</subject><subject>photocontrol</subject><subject>Porphyrins</subject><subject>self-assembly</subject><subject>Spectrometry, Fluorescence</subject><subject>supramolecular chemistry</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkb1uFDEURi1EREKgpURT0sxiz_XPTJlsQhIpWVAESmnZ42thmB0v9ixkXysPkmfCyYYVHVT3Xvl8p_BHyBtGZ4zS5r0ZA84aygQFyfgzcsBEw2pQCp6XnQPUqhVsn7zM-Vvh25bKF2S_kbTtGqAHBD99jVPs4zilOAzoqmv8iSkHO2A1j-PjHscq-mphxjitLVZmdI_HyqQp9IW7QhfMVLJ2U93f1fNNP0SHt1MKY3USlkXxiux5M2R8_TQPyZcPp5_n5_Xlx7OL-dFl3XPKeI1WduhpJ1zD25Yr2VkpLPfW29b3qlflzRlvWGMBnWgADQhqjGmtMN5ZOCTvtt5Vij_WmCe9DLnHYTAjxnXWTHEuVac6-A-UUgDOmSzobIv2Keac0OtVCkuTNppR_dCCfmhB71oogbdP7rVdotvhf769AN0W-BUG3PxDp48WF6d_y-ttNuQJb3dZk75rqUAJfbM40wDnxzfsWOhr-A18r6Vo</recordid><startdate>20150803</startdate><enddate>20150803</enddate><creator>Sun, He-Lue</creator><creator>Chen, Yong</creator><creator>Zhao, Jin</creator><creator>Liu, Yu</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150803</creationdate><title>Photocontrolled Reversible Conversion of Nanotube and Nanoparticle Mediated by β-Cyclodextrin Dimers</title><author>Sun, He-Lue ; Chen, Yong ; Zhao, Jin ; Liu, Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4014-eb69ef095d24884769b65b4fbfb8fc7c7f09dafa12b3ed523ea350aaa8b5afdb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Assembly</topic><topic>Azo Compounds - chemistry</topic><topic>beta-Cyclodextrins - chemistry</topic><topic>Circular Dichroism</topic><topic>Construction</topic><topic>Conversion</topic><topic>Derivatives</topic><topic>Dimerization</topic><topic>Irradiation</topic><topic>Isomerism</topic><topic>Light</topic><topic>Nanoparticles</topic><topic>Nanoparticles - chemistry</topic><topic>Nanoparticles - ultrastructure</topic><topic>Nanostructure</topic><topic>Nanotubes - chemistry</topic><topic>photochemistry</topic><topic>photocontrol</topic><topic>Porphyrins</topic><topic>self-assembly</topic><topic>Spectrometry, Fluorescence</topic><topic>supramolecular chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, He-Lue</creatorcontrib><creatorcontrib>Chen, Yong</creatorcontrib><creatorcontrib>Zhao, Jin</creatorcontrib><creatorcontrib>Liu, Yu</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, He-Lue</au><au>Chen, Yong</au><au>Zhao, Jin</au><au>Liu, Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photocontrolled Reversible Conversion of Nanotube and Nanoparticle Mediated by β-Cyclodextrin Dimers</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2015-08-03</date><risdate>2015</risdate><volume>54</volume><issue>32</issue><spage>9376</spage><epage>9380</epage><pages>9376-9380</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>A photochemically interconvertible supramolecular nanotube–nanoparticle system was constructed through secondary assembling of self‐aggregates of amphiphilic porphyrin derivatives mediated by trans‐ and cis‐azobenzene‐bridged bis(permethyl‐β‐cyclodextrin). Significantly, these nanotubes and nanoparticles were able to interconvert upon irradiation at different wavelengths, and this photocontrolled morphological conversion is reversible and recyclable for tens of times, which will provide a feasible and convenient way to construct the ordered nanostructure with various morphologies that can be smartly controlled by the environmentally benign external stimulus.
Photodriven interconversion: A photoswitchable supramolecular nanotube–nanoparticle system was constructed through secondary assembly of self‐aggregates of amphiphilic porphyrin derivatives (see picture). These nanoassemblies repeatedly interconvert upon irradiation at 365 and 450 nm.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>26089230</pmid><doi>10.1002/anie.201503614</doi><tpages>5</tpages></addata></record> |
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| subjects | Assembly Azo Compounds - chemistry beta-Cyclodextrins - chemistry Circular Dichroism Construction Conversion Derivatives Dimerization Irradiation Isomerism Light Nanoparticles Nanoparticles - chemistry Nanoparticles - ultrastructure Nanostructure Nanotubes - chemistry photochemistry photocontrol Porphyrins self-assembly Spectrometry, Fluorescence supramolecular chemistry |
| title | Photocontrolled Reversible Conversion of Nanotube and Nanoparticle Mediated by β-Cyclodextrin Dimers |
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