A Fluxional Copper Acetylide Cluster in CuAAC Catalysis

A molecularly defined copper acetylide cluster with ancillary N‐heterocyclic carbene (NHC) ligands was prepared under acidic reaction conditions. This cluster is the first molecular copper acetylide complex that features high activity in copper‐catalyzed azide–alkyne cycloadditions (CuAAC) with adde...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-06, Vol.54 (25), p.7431-7435
Hauptverfasser:	Makarem, Ata, Berg, Regina, Rominger, Frank, Straub, Bernd F.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetic acid Catalysis Catalytic activity click chemistry Clusters Coordination compounds Copper CuAAC Cycloaddition Ligands terminal alkynes
Online-Zugang:	Volltext
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