Aminobisphenolate supported tungsten disulphido and dithiolene complexes
Dioxotungsten(vi) complexes with tetradentate amino bisphenolates were converted into the corresponding Cs-symmetric amino bisphenolate disulphido complexes by a reaction with either Lawesson's reagent or P2S5. Further reaction with diethyl acetylenedicarboxylate leads to the formation of diama...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2015-05, Vol.44 (20), p.9409-9416 |
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| container_issue | 20 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 44 |
| creator | Salojärvi, E Peuronen, A Sillanpää, R Damlin, P Kivelä, H Lehtonen, A |
| description | Dioxotungsten(vi) complexes with tetradentate amino bisphenolates were converted into the corresponding Cs-symmetric amino bisphenolate disulphido complexes by a reaction with either Lawesson's reagent or P2S5. Further reaction with diethyl acetylenedicarboxylate leads to the formation of diamagnetic tungsten(iv) dithiolene compounds. The syntheses, crystal structures, spectroscopic and electrochemical characterization of such disulphido and dithiolene complexes are presented. |
| doi_str_mv | 10.1039/c5dt00995b |
| format | Article |
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Further reaction with diethyl acetylenedicarboxylate leads to the formation of diamagnetic tungsten(iv) dithiolene compounds. 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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2015-05, Vol.44 (20), p.9409-9416 |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Crystal structure Diamagnetism Electrochemical analysis Electrochemistry Formations Hydroxybenzoates - chemistry Models, Molecular Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxides - chemistry Spectroscopy Sulfides - chemistry Tungsten Tungsten - chemistry |
| title | Aminobisphenolate supported tungsten disulphido and dithiolene complexes |
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