Structures and charge–discharge properties of spin-carrying ferrocene derivatives
Ferrocene derivatives carrying TEMPO radical exhibited unique battery properties based on redox-active ferrocene and TEMPO units together with inherent magnetic properties. Several ferrocene derivatives (1–6) carrying nitroxide radical were prepared as dual redox compounds. They have distorted molec...
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| Veröffentlicht in: | Tetrahedron letters 2011-12, Vol.52 (49), p.6655-6658 |
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| creator | Fujiwara, Kazuya Akutsu, Hiroki Yamada, Jun-ichi Satoh, Masaharu Nakatsuji, Shin’ichi |
| description | Ferrocene derivatives carrying TEMPO radical exhibited unique battery properties based on redox-active ferrocene and TEMPO units together with inherent magnetic properties.
Several ferrocene derivatives (1–6) carrying nitroxide radical were prepared as dual redox compounds. They have distorted molecular structures and exhibit oxidation potentials based on both ferrocene and nitroxide groups except 4. The multi-step charge–discharge processes are discriminated for mono-substituted derivatives with the first discharge capacity up to 400Ahkg−1 for imino-derivative 3, while relatively characterless profiles are observed for bis-substituted derivatives 4 and 6 with capacity over 300Ahkg−1. |
| doi_str_mv | 10.1016/j.tetlet.2011.10.059 |
| format | Article |
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Several ferrocene derivatives (1–6) carrying nitroxide radical were prepared as dual redox compounds. They have distorted molecular structures and exhibit oxidation potentials based on both ferrocene and nitroxide groups except 4. The multi-step charge–discharge processes are discriminated for mono-substituted derivatives with the first discharge capacity up to 400Ahkg−1 for imino-derivative 3, while relatively characterless profiles are observed for bis-substituted derivatives 4 and 6 with capacity over 300Ahkg−1.</description><identifier>ISSN: 0040-4039</identifier><identifier>EISSN: 1873-3581</identifier><identifier>DOI: 10.1016/j.tetlet.2011.10.059</identifier><identifier>CODEN: TELEAY</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Chemistry ; Crystal structure ; Derivatives ; Direct energy conversion and energy accumulation ; Discharge ; Distortion ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrochemistry ; Electrode potentials ; Exact sciences and technology ; Ferrocene ; Ferrocenes ; Free radicals chemistry ; General and physical chemistry ; Heterocyclic compounds ; Heterocyclic compounds with only one n hetero atom and condensed derivatives ; Magnetic property ; Molecular structure ; Nitroxide radical ; Organic chemistry ; Preparations and properties ; Radicals ; Reactivity and mechanisms ; Redox property ; Secondary battery ; Tetrahedrons</subject><ispartof>Tetrahedron letters, 2011-12, Vol.52 (49), p.6655-6658</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c435t-9cdae8fcdebc2ab96756e8fd9dc4127df46f8975a737cd55aa50d63cc197269b3</citedby><cites>FETCH-LOGICAL-c435t-9cdae8fcdebc2ab96756e8fd9dc4127df46f8975a737cd55aa50d63cc197269b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.tetlet.2011.10.059$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24775747$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Fujiwara, Kazuya</creatorcontrib><creatorcontrib>Akutsu, Hiroki</creatorcontrib><creatorcontrib>Yamada, Jun-ichi</creatorcontrib><creatorcontrib>Satoh, Masaharu</creatorcontrib><creatorcontrib>Nakatsuji, Shin’ichi</creatorcontrib><title>Structures and charge–discharge properties of spin-carrying ferrocene derivatives</title><title>Tetrahedron letters</title><description>Ferrocene derivatives carrying TEMPO radical exhibited unique battery properties based on redox-active ferrocene and TEMPO units together with inherent magnetic properties.
Several ferrocene derivatives (1–6) carrying nitroxide radical were prepared as dual redox compounds. They have distorted molecular structures and exhibit oxidation potentials based on both ferrocene and nitroxide groups except 4. The multi-step charge–discharge processes are discriminated for mono-substituted derivatives with the first discharge capacity up to 400Ahkg−1 for imino-derivative 3, while relatively characterless profiles are observed for bis-substituted derivatives 4 and 6 with capacity over 300Ahkg−1.</description><subject>Applied sciences</subject><subject>Chemistry</subject><subject>Crystal structure</subject><subject>Derivatives</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Discharge</subject><subject>Distortion</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrochemistry</subject><subject>Electrode potentials</subject><subject>Exact sciences and technology</subject><subject>Ferrocene</subject><subject>Ferrocenes</subject><subject>Free radicals chemistry</subject><subject>General and physical chemistry</subject><subject>Heterocyclic compounds</subject><subject>Heterocyclic compounds with only one n hetero atom and condensed derivatives</subject><subject>Magnetic property</subject><subject>Molecular structure</subject><subject>Nitroxide radical</subject><subject>Organic chemistry</subject><subject>Preparations and properties</subject><subject>Radicals</subject><subject>Reactivity and mechanisms</subject><subject>Redox property</subject><subject>Secondary battery</subject><subject>Tetrahedrons</subject><issn>0040-4039</issn><issn>1873-3581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKLDEQhoMcwTmjb-CiN4KbHpNO0uneCCLHCwgu1HXIVKo1Q9s9VjID7nwH39AnMUPLWVqbuvDV7WfsWPCF4KI-Wy0Sph7TouJC5NKC63aPzURjZCl1I_6wGeeKl4rL9oD9jXHFs9UNn7GHh0QbSBvCWLjBF_Di6Bm_Pj59iFNcrGlcI6WQibEr4joMJTii9zA8Fx0SjYADFh4pbF0KW4yHbL9zfcSjHz9nT1f_Hi9vyrv769vLi7sSlNSpbME7bDrwuITKLdva6DrnvvWgRGV8p-quaY12RhrwWjunua8lgGhNVbdLOWen09x84dsGY7Kv-WjsezfguIlWGKVq08hKZlRNKNAYI2Fn1xReHb1bwe1OQ7uyk4Z2p-GumjXMbSc_G1wE13fkBgjxf2-ljNFGmcydTxzmd7cByUYIOAD6QAjJ-jH8vugb77CM4A</recordid><startdate>20111207</startdate><enddate>20111207</enddate><creator>Fujiwara, Kazuya</creator><creator>Akutsu, Hiroki</creator><creator>Yamada, Jun-ichi</creator><creator>Satoh, Masaharu</creator><creator>Nakatsuji, Shin’ichi</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20111207</creationdate><title>Structures and charge–discharge properties of spin-carrying ferrocene derivatives</title><author>Fujiwara, Kazuya ; Akutsu, Hiroki ; Yamada, Jun-ichi ; Satoh, Masaharu ; Nakatsuji, Shin’ichi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-9cdae8fcdebc2ab96756e8fd9dc4127df46f8975a737cd55aa50d63cc197269b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Crystal structure</topic><topic>Derivatives</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Discharge</topic><topic>Distortion</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrochemistry</topic><topic>Electrode potentials</topic><topic>Exact sciences and technology</topic><topic>Ferrocene</topic><topic>Ferrocenes</topic><topic>Free radicals chemistry</topic><topic>General and physical chemistry</topic><topic>Heterocyclic compounds</topic><topic>Heterocyclic compounds with only one n hetero atom and condensed derivatives</topic><topic>Magnetic property</topic><topic>Molecular structure</topic><topic>Nitroxide radical</topic><topic>Organic chemistry</topic><topic>Preparations and properties</topic><topic>Radicals</topic><topic>Reactivity and mechanisms</topic><topic>Redox property</topic><topic>Secondary battery</topic><topic>Tetrahedrons</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fujiwara, Kazuya</creatorcontrib><creatorcontrib>Akutsu, Hiroki</creatorcontrib><creatorcontrib>Yamada, Jun-ichi</creatorcontrib><creatorcontrib>Satoh, Masaharu</creatorcontrib><creatorcontrib>Nakatsuji, Shin’ichi</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Tetrahedron letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fujiwara, Kazuya</au><au>Akutsu, Hiroki</au><au>Yamada, Jun-ichi</au><au>Satoh, Masaharu</au><au>Nakatsuji, Shin’ichi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structures and charge–discharge properties of spin-carrying ferrocene derivatives</atitle><jtitle>Tetrahedron letters</jtitle><date>2011-12-07</date><risdate>2011</risdate><volume>52</volume><issue>49</issue><spage>6655</spage><epage>6658</epage><pages>6655-6658</pages><issn>0040-4039</issn><eissn>1873-3581</eissn><coden>TELEAY</coden><abstract>Ferrocene derivatives carrying TEMPO radical exhibited unique battery properties based on redox-active ferrocene and TEMPO units together with inherent magnetic properties.
Several ferrocene derivatives (1–6) carrying nitroxide radical were prepared as dual redox compounds. They have distorted molecular structures and exhibit oxidation potentials based on both ferrocene and nitroxide groups except 4. The multi-step charge–discharge processes are discriminated for mono-substituted derivatives with the first discharge capacity up to 400Ahkg−1 for imino-derivative 3, while relatively characterless profiles are observed for bis-substituted derivatives 4 and 6 with capacity over 300Ahkg−1.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.tetlet.2011.10.059</doi><tpages>4</tpages></addata></record> |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Applied sciences Chemistry Crystal structure Derivatives Direct energy conversion and energy accumulation Discharge Distortion Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrochemistry Electrode potentials Exact sciences and technology Ferrocene Ferrocenes Free radicals chemistry General and physical chemistry Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Magnetic property Molecular structure Nitroxide radical Organic chemistry Preparations and properties Radicals Reactivity and mechanisms Redox property Secondary battery Tetrahedrons |
| title | Structures and charge–discharge properties of spin-carrying ferrocene derivatives |
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