Recent advances in copper-catalyzed propargylic substitution
[Display omitted] The copper-catalyzed propargylic substitution reaction has become a powerful synthetic method to prepare the compounds containing the propargylic subunit. Compared with the other transition-metals applied in the propargylic substitution, copper has many obvious advantages, such as...
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| Veröffentlicht in: | Tetrahedron letters 2015-01, Vol.56 (2), p.283-295 |
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| creator | Zhang, De-Yang Hu, Xiang-Ping |
| description | [Display omitted]
The copper-catalyzed propargylic substitution reaction has become a powerful synthetic method to prepare the compounds containing the propargylic subunit. Compared with the other transition-metals applied in the propargylic substitution, copper has many obvious advantages, such as much more inexpensive, easier to handle, milder reaction condition, and higher selectivity. This digest summarizes the recent development in the copper-catalyzed propargylic substitutions with various nitrogen, carbon, oxygen, and sulfur nucleophiles. In addition, the cycloadditions involving the copper-catalyzed propargylic substitution as the key step are included. |
| doi_str_mv | 10.1016/j.tetlet.2014.11.112 |
| format | Article |
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The copper-catalyzed propargylic substitution reaction has become a powerful synthetic method to prepare the compounds containing the propargylic subunit. Compared with the other transition-metals applied in the propargylic substitution, copper has many obvious advantages, such as much more inexpensive, easier to handle, milder reaction condition, and higher selectivity. This digest summarizes the recent development in the copper-catalyzed propargylic substitutions with various nitrogen, carbon, oxygen, and sulfur nucleophiles. In addition, the cycloadditions involving the copper-catalyzed propargylic substitution as the key step are included.</description><identifier>ISSN: 0040-4039</identifier><identifier>EISSN: 1873-3581</identifier><identifier>DOI: 10.1016/j.tetlet.2014.11.112</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Asymmetric catalysis ; C-Nucleophiles ; Carbon ; Copper ; Cycloaddition ; Handles ; N-Nucleophiles ; Nucleophiles ; Propargylic substitution ; Selectivity ; Sulfur ; Tetrahedrons</subject><ispartof>Tetrahedron letters, 2015-01, Vol.56 (2), p.283-295</ispartof><rights>2014</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c595t-cda9d1d5a5ff1c37b3bbcdeefe43f848652db79a0085b03ecb88c925006a9d803</citedby><cites>FETCH-LOGICAL-c595t-cda9d1d5a5ff1c37b3bbcdeefe43f848652db79a0085b03ecb88c925006a9d803</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0040403914020267$$EHTML$$P50$$Gelsevier$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Zhang, De-Yang</creatorcontrib><creatorcontrib>Hu, Xiang-Ping</creatorcontrib><title>Recent advances in copper-catalyzed propargylic substitution</title><title>Tetrahedron letters</title><description>[Display omitted]
The copper-catalyzed propargylic substitution reaction has become a powerful synthetic method to prepare the compounds containing the propargylic subunit. Compared with the other transition-metals applied in the propargylic substitution, copper has many obvious advantages, such as much more inexpensive, easier to handle, milder reaction condition, and higher selectivity. This digest summarizes the recent development in the copper-catalyzed propargylic substitutions with various nitrogen, carbon, oxygen, and sulfur nucleophiles. In addition, the cycloadditions involving the copper-catalyzed propargylic substitution as the key step are included.</description><subject>Asymmetric catalysis</subject><subject>C-Nucleophiles</subject><subject>Carbon</subject><subject>Copper</subject><subject>Cycloaddition</subject><subject>Handles</subject><subject>N-Nucleophiles</subject><subject>Nucleophiles</subject><subject>Propargylic substitution</subject><subject>Selectivity</subject><subject>Sulfur</subject><subject>Tetrahedrons</subject><issn>0040-4039</issn><issn>1873-3581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-Aw89emlNmmSbggiy-A8WBNFzSCdTydJta5IurJ_eLPXs8GAu7z1mfoRcM1owyla32yJi7DAWJWWiYCypPCELpiqec6nYKVlQKmguKK_PyUUIW5pmpeiC3L0jYB8zY_emBwyZ6zMYxhF9Diaa7vCDNhv9MBr_degcZGFqQnRxim7oL8lZa7qAV397ST6fHj_WL_nm7fl1_bDJQdYy5mBNbZmVRrYtA141vGnAIrYoeKuEWsnSNlVtKFWyoRyhUQrqUqYTU1BRviQ3c2865HvCEPXOBcCuMz0OU9CsEmJVVUKVySpmK_ghBI-tHr3bGX_QjOojLL3VMyx9hKUZSzrG7ucYpjf2Dr0O4DABsc4jRG0H93_BL62bdjQ</recordid><startdate>20150108</startdate><enddate>20150108</enddate><creator>Zhang, De-Yang</creator><creator>Hu, Xiang-Ping</creator><general>Elsevier Ltd</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150108</creationdate><title>Recent advances in copper-catalyzed propargylic substitution</title><author>Zhang, De-Yang ; Hu, Xiang-Ping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c595t-cda9d1d5a5ff1c37b3bbcdeefe43f848652db79a0085b03ecb88c925006a9d803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Asymmetric catalysis</topic><topic>C-Nucleophiles</topic><topic>Carbon</topic><topic>Copper</topic><topic>Cycloaddition</topic><topic>Handles</topic><topic>N-Nucleophiles</topic><topic>Nucleophiles</topic><topic>Propargylic substitution</topic><topic>Selectivity</topic><topic>Sulfur</topic><topic>Tetrahedrons</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, De-Yang</creatorcontrib><creatorcontrib>Hu, Xiang-Ping</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Tetrahedron letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, De-Yang</au><au>Hu, Xiang-Ping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent advances in copper-catalyzed propargylic substitution</atitle><jtitle>Tetrahedron letters</jtitle><date>2015-01-08</date><risdate>2015</risdate><volume>56</volume><issue>2</issue><spage>283</spage><epage>295</epage><pages>283-295</pages><issn>0040-4039</issn><eissn>1873-3581</eissn><abstract>[Display omitted]
The copper-catalyzed propargylic substitution reaction has become a powerful synthetic method to prepare the compounds containing the propargylic subunit. Compared with the other transition-metals applied in the propargylic substitution, copper has many obvious advantages, such as much more inexpensive, easier to handle, milder reaction condition, and higher selectivity. This digest summarizes the recent development in the copper-catalyzed propargylic substitutions with various nitrogen, carbon, oxygen, and sulfur nucleophiles. In addition, the cycloadditions involving the copper-catalyzed propargylic substitution as the key step are included.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.tetlet.2014.11.112</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Tetrahedron letters, 2015-01, Vol.56 (2), p.283-295 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Asymmetric catalysis C-Nucleophiles Carbon Copper Cycloaddition Handles N-Nucleophiles Nucleophiles Propargylic substitution Selectivity Sulfur Tetrahedrons |
| title | Recent advances in copper-catalyzed propargylic substitution |
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