Mechanistic insights into hydride transfer for catalytic hydrogenation of CO sub(2) with cobalt complexes

The catalytic hydrogenation of CO sub(2) to formate by Co(dmpe) sub(2)H can proceed viadirect hydride transfer or viaCO sub(2) coordination to Co followed by reductive elimination of formate. The different nature of the rate-determining step in the two mechanisms may provide new insights into design...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-07, Vol.43 (31), p.11803-11806
Hauptverfasser:	Kumar, N, Camaioni, D M, Dupuis, M, Raugei, S, Appel, A M
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon dioxide Carbon monoxide Catalysis Catalysts Cobalt Formates Hydrides Hydrogenation
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description	The catalytic hydrogenation of CO sub(2) to formate by Co(dmpe) sub(2)H can proceed viadirect hydride transfer or viaCO sub(2) coordination to Co followed by reductive elimination of formate. The different nature of the rate-determining step in the two mechanisms may provide new insights into designing catalysts with improved performance.
doi_str_mv	10.1039/c4dt01551g
format	Article
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Carbon dioxide Carbon monoxide Catalysis Catalysts Cobalt Formates Hydrides Hydrogenation
title	Mechanistic insights into hydride transfer for catalytic hydrogenation of CO sub(2) with cobalt complexes
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