The first total synthesis and structural determination of epi-cochlioquinone A

The first total synthesis of epi-cochlioquinone A has been achieved in a highly convergent manner via [3+3] cycloaddition of catechol 2 and oxadecalin 3 as the key reaction. The synthesis of the catechol segment, possessing the side chain with multi stereogenic centers, features the asymmetric vinyl...

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Veröffentlicht in:	Tetrahedron letters 2010-10, Vol.51 (42), p.5532-5536
Hauptverfasser:	Hosokawa, Seijiro, Matsushita, Kaoru, Tokimatsu, Shinpei, Toriumi, Tatsuya, Suzuki, Yasuaki, Tatsuta, Kuniaki
Format:	Artikel
Sprache:	eng
Schlagworte:	[3+3] Annulation Aldehydes Autocatalysis Catechol Cycloaddition Epi-cochlioquinone A Nitro-Dieckmann condensation Nitroalkene Organic chemistry Oxidation Segments Synthesis Total synthesis Transformations Vinylogous Mukaiyama aldol reaction
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