Biogenous iron oxide-immobilized palladium catalyst for the solvent-free Suzuki–Miyaura coupling reaction
Iron oxide produced by iron-oxidizing bacteria, Leptothrix ochracea, (biogenous iron oxide: BIO) was used as a support for immobilized palladium catalysts with organic cross-linkers. Palladium immobilized on BIO bearing imidazolium chloride delivered the desired biaryl products in sufficient yields...
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| Veröffentlicht in: | Tetrahedron letters 2012-01, Vol.53 (3), p.329-332 |
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| creator | Mandai, Kyoko Korenaga, Toshinobu Ema, Tadashi Sakai, Takashi Furutani, Mitsuaki Hashimoto, Hideki Takada, Jun |
| description | Iron oxide produced by iron-oxidizing bacteria,
Leptothrix ochracea, (biogenous iron oxide: BIO) was used as a support for immobilized palladium catalysts with organic cross-linkers. Palladium immobilized on BIO bearing imidazolium chloride delivered the desired biaryl products in sufficient yields in the Suzuki–Miyaura coupling reactions under solvent-free conditions and could be reused several times without significant loss of catalytic activity. It is shown that BIO can be exploited as a useful support for immobilization of palladium and the BIO-immobilized palladium catalyst effectively promotes the solvent-free Suzuki–Miyaura coupling reactions. |
| doi_str_mv | 10.1016/j.tetlet.2011.11.044 |
| format | Article |
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Leptothrix ochracea, (biogenous iron oxide: BIO) was used as a support for immobilized palladium catalysts with organic cross-linkers. Palladium immobilized on BIO bearing imidazolium chloride delivered the desired biaryl products in sufficient yields in the Suzuki–Miyaura coupling reactions under solvent-free conditions and could be reused several times without significant loss of catalytic activity. It is shown that BIO can be exploited as a useful support for immobilization of palladium and the BIO-immobilized palladium catalyst effectively promotes the solvent-free Suzuki–Miyaura coupling reactions.</description><identifier>ISSN: 0040-4039</identifier><identifier>EISSN: 1873-3581</identifier><identifier>DOI: 10.1016/j.tetlet.2011.11.044</identifier><identifier>CODEN: TELEAY</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Bacteria ; Biogenous iron oxide ; Catalysis ; Catalysts ; Catalysts: preparations and properties ; Chemical reactions ; Chemistry ; Chlorides ; Exact sciences and technology ; General and physical chemistry ; Heterocyclic compounds ; Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings ; Immobilized catalyst ; Iron ; Iron oxides ; Noncondensed benzenic compounds ; Organic chemistry ; Palladium ; Palladium catalyst ; Preparations and properties ; Solvent-free reaction ; Suzuki–Miyaura coupling reaction ; Tetrahedrons ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Tetrahedron letters, 2012-01, Vol.53 (3), p.329-332</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c369t-9d0f64334bc6b498448573bb5094945a4a02ae78552c006313910ad2932c9b0b3</citedby><cites>FETCH-LOGICAL-c369t-9d0f64334bc6b498448573bb5094945a4a02ae78552c006313910ad2932c9b0b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.tetlet.2011.11.044$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25369822$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Mandai, Kyoko</creatorcontrib><creatorcontrib>Korenaga, Toshinobu</creatorcontrib><creatorcontrib>Ema, Tadashi</creatorcontrib><creatorcontrib>Sakai, Takashi</creatorcontrib><creatorcontrib>Furutani, Mitsuaki</creatorcontrib><creatorcontrib>Hashimoto, Hideki</creatorcontrib><creatorcontrib>Takada, Jun</creatorcontrib><title>Biogenous iron oxide-immobilized palladium catalyst for the solvent-free Suzuki–Miyaura coupling reaction</title><title>Tetrahedron letters</title><description>Iron oxide produced by iron-oxidizing bacteria,
Leptothrix ochracea, (biogenous iron oxide: BIO) was used as a support for immobilized palladium catalysts with organic cross-linkers. Palladium immobilized on BIO bearing imidazolium chloride delivered the desired biaryl products in sufficient yields in the Suzuki–Miyaura coupling reactions under solvent-free conditions and could be reused several times without significant loss of catalytic activity. It is shown that BIO can be exploited as a useful support for immobilization of palladium and the BIO-immobilized palladium catalyst effectively promotes the solvent-free Suzuki–Miyaura coupling reactions.</description><subject>Bacteria</subject><subject>Biogenous iron oxide</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalysts: preparations and properties</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chlorides</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Heterocyclic compounds</subject><subject>Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings</subject><subject>Immobilized catalyst</subject><subject>Iron</subject><subject>Iron oxides</subject><subject>Noncondensed benzenic compounds</subject><subject>Organic chemistry</subject><subject>Palladium</subject><subject>Palladium catalyst</subject><subject>Preparations and properties</subject><subject>Solvent-free reaction</subject><subject>Suzuki–Miyaura coupling reaction</subject><subject>Tetrahedrons</subject><subject>Theory of reactions, general kinetics. 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Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mandai, Kyoko</creatorcontrib><creatorcontrib>Korenaga, Toshinobu</creatorcontrib><creatorcontrib>Ema, Tadashi</creatorcontrib><creatorcontrib>Sakai, Takashi</creatorcontrib><creatorcontrib>Furutani, Mitsuaki</creatorcontrib><creatorcontrib>Hashimoto, Hideki</creatorcontrib><creatorcontrib>Takada, Jun</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Tetrahedron letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mandai, Kyoko</au><au>Korenaga, Toshinobu</au><au>Ema, Tadashi</au><au>Sakai, Takashi</au><au>Furutani, Mitsuaki</au><au>Hashimoto, Hideki</au><au>Takada, Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biogenous iron oxide-immobilized palladium catalyst for the solvent-free Suzuki–Miyaura coupling reaction</atitle><jtitle>Tetrahedron letters</jtitle><date>2012-01-18</date><risdate>2012</risdate><volume>53</volume><issue>3</issue><spage>329</spage><epage>332</epage><pages>329-332</pages><issn>0040-4039</issn><eissn>1873-3581</eissn><coden>TELEAY</coden><abstract>Iron oxide produced by iron-oxidizing bacteria,
Leptothrix ochracea, (biogenous iron oxide: BIO) was used as a support for immobilized palladium catalysts with organic cross-linkers. Palladium immobilized on BIO bearing imidazolium chloride delivered the desired biaryl products in sufficient yields in the Suzuki–Miyaura coupling reactions under solvent-free conditions and could be reused several times without significant loss of catalytic activity. It is shown that BIO can be exploited as a useful support for immobilization of palladium and the BIO-immobilized palladium catalyst effectively promotes the solvent-free Suzuki–Miyaura coupling reactions.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.tetlet.2011.11.044</doi><tpages>4</tpages></addata></record> |
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| ispartof | Tetrahedron letters, 2012-01, Vol.53 (3), p.329-332 |
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| subjects | Bacteria Biogenous iron oxide Catalysis Catalysts Catalysts: preparations and properties Chemical reactions Chemistry Chlorides Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Immobilized catalyst Iron Iron oxides Noncondensed benzenic compounds Organic chemistry Palladium Palladium catalyst Preparations and properties Solvent-free reaction Suzuki–Miyaura coupling reaction Tetrahedrons Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Biogenous iron oxide-immobilized palladium catalyst for the solvent-free Suzuki–Miyaura coupling reaction |
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