Synthesis of β-hydroxyphosphonates by iron-catalyzed oxidative addition of phosphonyl radicals to alkenes
Phosphorohydrazidates have been shown to work as radical precursors by iron-catalyzed aerobic oxidation to generate corresponding phosphonyl radicals. Generated radicals cause intermolecular addition to various alkenes in the presence of molecular oxygen to give β-hydroxyphosphonate compounds in goo...
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| Veröffentlicht in: | Tetrahedron letters 2011-09, Vol.52 (37), p.4768-4770 |
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| container_issue | 37 |
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| container_title | Tetrahedron letters |
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| creator | Taniguchi, Tsuyoshi Idota, Atsushi Yokoyama, Shin’ichi Ishibashi, Hiroyuki |
| description | Phosphorohydrazidates have been shown to work as radical precursors by iron-catalyzed aerobic oxidation to generate corresponding phosphonyl radicals. Generated radicals cause intermolecular addition to various alkenes in the presence of molecular oxygen to give β-hydroxyphosphonate compounds in good yield. |
| doi_str_mv | 10.1016/j.tetlet.2011.07.026 |
| format | Article |
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| ispartof | Tetrahedron letters, 2011-09, Vol.52 (37), p.4768-4770 |
| issn | 0040-4039 1873-3581 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Alkenes Chemistry Exact sciences and technology Free radicals chemistry Iron catalysis Organic chemistry Organometalloidal and organometallic compounds Oxidation Oxygenation P derivatives Phosphonates Precursors Preparations and properties Radical reactions Radicals Reactivity and mechanisms Synthesis (chemistry) Tetrahedrons |
| title | Synthesis of β-hydroxyphosphonates by iron-catalyzed oxidative addition of phosphonyl radicals to alkenes |
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