Nanofluorides

The chemistry, physics and technology of nanofluorides intensively develops last years. This process is illustrated by exponential growth of number of publications ( n) on this theme. [Display omitted] ► Number of publications about nanofluorides grew exponentially over last 10 years. ► Current stat...

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Veröffentlicht in:Journal of fluorine chemistry 2011-12, Vol.132 (12), p.1012-1039
Hauptverfasser: Fedorov, Pavel P., Luginina, Anna A., Kuznetsov, Sergei V., Osiko, Vyacheslav V.
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container_end_page 1039
container_issue 12
container_start_page 1012
container_title Journal of fluorine chemistry
container_volume 132
creator Fedorov, Pavel P.
Luginina, Anna A.
Kuznetsov, Sergei V.
Osiko, Vyacheslav V.
description The chemistry, physics and technology of nanofluorides intensively develops last years. This process is illustrated by exponential growth of number of publications ( n) on this theme. [Display omitted] ► Number of publications about nanofluorides grew exponentially over last 10 years. ► Current state of nanofluoride chemistry and material science has been reviewed. ► Chemically active nanofluoride phases are formed in non-equilibrium systems. ► Control of nanofluoride phase composition must be accompanied by chemical analysis. ► Nanofluoride syntheses and use in optics, catalysis and medicine have been discussed. The present review article covers major aspects of inorganic chemistry of nanofluorides, including methods of their synthesis (thermolysis of the precursors, co-precipitation from solutions, reversed micelle technique, hydro- and solvo-thermal techniques, sol–gel method, etc.), nanochemical effects (enhanced chemical activity, self-organization and self-assembly, non-classical mechanism of the single crystal growth, synthesis of non-equilibrium phases), targeted preparation of 1D, 2D, and 3D nanostructures, surface modification of the nanoparticles, fluoride nanocomposites (glass- and nano-ceramics) as well as applications of nanofluorides.
doi_str_mv 10.1016/j.jfluchem.2011.06.025
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subjects Inorganic fluorides
Nanocomposites
Nanofluorides
Nanoparticles
Nanostructure
Phases
Self assembly
Surface chemistry
Synthesis
Three dimensional
Up-conversion
title Nanofluorides
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