Recyclable silica-supported iodoarene-RuCl sub(3 bifunctional catalysts for oxidation of alcohols and alkylarenes)

Novel, efficient, and recyclable bifunctional catalysts bearing SiO sub(2-supported RuCl) sub(3) and iodoarene moieties were developed and used for environmentally benign oxidation of alcohols or alkylarenes at the benzylic position. These reactions in the presence of oxone as stoichiometric oxidant...

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Veröffentlicht in:Tetrahedron letters 2011-10, Vol.52 (43), p.5652-5655
Hauptverfasser: Zeng, Xiao-Mei, Chen, Jiang-Min, Middleton, Kyle, Zhdankin, Viktor V
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container_issue 43
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container_title Tetrahedron letters
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creator Zeng, Xiao-Mei
Chen, Jiang-Min
Middleton, Kyle
Zhdankin, Viktor V
description Novel, efficient, and recyclable bifunctional catalysts bearing SiO sub(2-supported RuCl) sub(3) and iodoarene moieties were developed and used for environmentally benign oxidation of alcohols or alkylarenes at the benzylic position. These reactions in the presence of oxone as stoichiometric oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient work-up. Furthermore, these SiO sub(2-supported bifunctional catalysts can be recovered by simple filtration and directly reused.)
doi_str_mv 10.1016/j.tetlet.2011.08.097
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subjects Alcohols
Carbonyl compounds
Catalysis
Catalysts
Filtration
Oxidation
Silicon dioxide
Tetrahedrons
title Recyclable silica-supported iodoarene-RuCl sub(3 bifunctional catalysts for oxidation of alcohols and alkylarenes)
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