Total synthesis of (−)-cleistenolide

Total synthesis of (−)-cleistenolide

The total synthesis of (−)-cleistenolide, a novel natural product recently isolated from the annonaceae species cleistochlamys kirkii oliver, is described. The synthesis proceeds starting from easily accessible d-manitol using a selective benzoylation, a selective acetonide deprotection, silylprotec...

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Veröffentlicht in:Tetrahedron letters 2011-05, Vol.52 (19), p.2443-2445
Hauptverfasser: Ramesh, Palakuri, Meshram, H.M.
Format: Artikel
Sprache:eng
Schlagworte:
Accessibility
Benzoylation
Chemistry
Decomposition reactions
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Metathesis
Natural products
Organic chemistry
Preparations and properties
Synthesis (chemistry)
Tetrahedrons
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Beschreibung
Zusammenfassung:The total synthesis of (−)-cleistenolide, a novel natural product recently isolated from the annonaceae species cleistochlamys kirkii oliver, is described. The synthesis proceeds starting from easily accessible d-manitol using a selective benzoylation, a selective acetonide deprotection, silylprotection and ring-closing metathesis reaction.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2011.01.124