Variation of guest selectivity within [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages through subtle modification of the face-capping ligand

Variation of guest selectivity within [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages through subtle modification of the face-capping ligand

We report here the host-guest behaviour of two isoelectronic [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages that differ only in the nature of their face-capping ligand and possess either triazine (L1) or benzene (L2) cores. Crystallography reveals these hosts to be flexible and adaptable, while NM...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2014-09, Vol.43 (39), p.14550-14553
Hauptverfasser: Ferguson, Alan, Staniland, Robert W, Fitchett, Christopher M, Squire, Marie A, Williamson, Bryce E, Kruger, Paul E
Format: Artikel
Sprache:eng
Schlagworte:
Benzene
Cages
Crystallography
Ligands
NMR spectroscopy
Selectivity
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 14553
container_issue 39
container_start_page 14550
container_title Dalton transactions : an international journal of inorganic chemistry
container_volume 43
creator Ferguson, Alan
Staniland, Robert W
Fitchett, Christopher M
Squire, Marie A
Williamson, Bryce E
Kruger, Paul E
description We report here the host-guest behaviour of two isoelectronic [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages that differ only in the nature of their face-capping ligand and possess either triazine (L1) or benzene (L2) cores. Crystallography reveals these hosts to be flexible and adaptable, while NMR spectroscopy shows them to be selective and discriminating in their host-guest behaviour.
doi_str_mv 10.1039/c4dt02337d
format Article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_1744675093</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1744675093</sourcerecordid><originalsourceid>FETCH-proquest_miscellaneous_17446750933</originalsourceid><addsrcrecordid>eNqVjr1OwzAURi0EEuVn4QnumAoFHNttyIyoOjAiFoQqY98kF7lxsG9APATvDJWq7kznG450PiGuKnlTSd3cOuNZKq1rfyRmlanrslHaHB-2Wp6Ks5zfpVRKLtRM_DzbRJYpDhBb6CbMDBkDOqZP4m_4Iu5pgJcVQp7eCjN_3PP1jyOm4g6u58DIyfbokw3gbIcZuE9x6vqdzAFhGz215A4h7hFa67B0dhxp6CBQZwd_IU5aGzJe7nkuitXD0_26HFP82H3bbCk7DMEOGKe8qWpjlvVCNlr_Q_0FpwNd1w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1744675093</pqid></control><display><type>article</type><title>Variation of guest selectivity within [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages through subtle modification of the face-capping ligand</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Ferguson, Alan ; Staniland, Robert W ; Fitchett, Christopher M ; Squire, Marie A ; Williamson, Bryce E ; Kruger, Paul E</creator><creatorcontrib>Ferguson, Alan ; Staniland, Robert W ; Fitchett, Christopher M ; Squire, Marie A ; Williamson, Bryce E ; Kruger, Paul E</creatorcontrib><description>We report here the host-guest behaviour of two isoelectronic [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages that differ only in the nature of their face-capping ligand and possess either triazine (L1) or benzene (L2) cores. Crystallography reveals these hosts to be flexible and adaptable, while NMR spectroscopy shows them to be selective and discriminating in their host-guest behaviour.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c4dt02337d</identifier><language>eng</language><subject>Benzene ; Cages ; Crystallography ; Ligands ; NMR spectroscopy ; Selectivity</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2014-09, Vol.43 (39), p.14550-14553</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Ferguson, Alan</creatorcontrib><creatorcontrib>Staniland, Robert W</creatorcontrib><creatorcontrib>Fitchett, Christopher M</creatorcontrib><creatorcontrib>Squire, Marie A</creatorcontrib><creatorcontrib>Williamson, Bryce E</creatorcontrib><creatorcontrib>Kruger, Paul E</creatorcontrib><title>Variation of guest selectivity within [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages through subtle modification of the face-capping ligand</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>We report here the host-guest behaviour of two isoelectronic [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages that differ only in the nature of their face-capping ligand and possess either triazine (L1) or benzene (L2) cores. Crystallography reveals these hosts to be flexible and adaptable, while NMR spectroscopy shows them to be selective and discriminating in their host-guest behaviour.</description><subject>Benzene</subject><subject>Cages</subject><subject>Crystallography</subject><subject>Ligands</subject><subject>NMR spectroscopy</subject><subject>Selectivity</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqVjr1OwzAURi0EEuVn4QnumAoFHNttyIyoOjAiFoQqY98kF7lxsG9APATvDJWq7kznG450PiGuKnlTSd3cOuNZKq1rfyRmlanrslHaHB-2Wp6Ks5zfpVRKLtRM_DzbRJYpDhBb6CbMDBkDOqZP4m_4Iu5pgJcVQp7eCjN_3PP1jyOm4g6u58DIyfbokw3gbIcZuE9x6vqdzAFhGz215A4h7hFa67B0dhxp6CBQZwd_IU5aGzJe7nkuitXD0_26HFP82H3bbCk7DMEOGKe8qWpjlvVCNlr_Q_0FpwNd1w</recordid><startdate>20140901</startdate><enddate>20140901</enddate><creator>Ferguson, Alan</creator><creator>Staniland, Robert W</creator><creator>Fitchett, Christopher M</creator><creator>Squire, Marie A</creator><creator>Williamson, Bryce E</creator><creator>Kruger, Paul E</creator><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140901</creationdate><title>Variation of guest selectivity within [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages through subtle modification of the face-capping ligand</title><author>Ferguson, Alan ; Staniland, Robert W ; Fitchett, Christopher M ; Squire, Marie A ; Williamson, Bryce E ; Kruger, Paul E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_17446750933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Benzene</topic><topic>Cages</topic><topic>Crystallography</topic><topic>Ligands</topic><topic>NMR spectroscopy</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ferguson, Alan</creatorcontrib><creatorcontrib>Staniland, Robert W</creatorcontrib><creatorcontrib>Fitchett, Christopher M</creatorcontrib><creatorcontrib>Squire, Marie A</creatorcontrib><creatorcontrib>Williamson, Bryce E</creatorcontrib><creatorcontrib>Kruger, Paul E</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ferguson, Alan</au><au>Staniland, Robert W</au><au>Fitchett, Christopher M</au><au>Squire, Marie A</au><au>Williamson, Bryce E</au><au>Kruger, Paul E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Variation of guest selectivity within [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages through subtle modification of the face-capping ligand</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2014-09-01</date><risdate>2014</risdate><volume>43</volume><issue>39</issue><spage>14550</spage><epage>14553</epage><pages>14550-14553</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>We report here the host-guest behaviour of two isoelectronic [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages that differ only in the nature of their face-capping ligand and possess either triazine (L1) or benzene (L2) cores. Crystallography reveals these hosts to be flexible and adaptable, while NMR spectroscopy shows them to be selective and discriminating in their host-guest behaviour.</abstract><doi>10.1039/c4dt02337d</doi></addata></record>
fulltext fulltext
identifier ISSN: 1477-9226
ispartof Dalton transactions : an international journal of inorganic chemistry, 2014-09, Vol.43 (39), p.14550-14553
issn 1477-9226
1477-9234
language eng
recordid cdi_proquest_miscellaneous_1744675093
source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Benzene
Cages
Crystallography
Ligands
NMR spectroscopy
Selectivity
title Variation of guest selectivity within [Fe sub(4)L sub(4)] super(8 +) tetrahedral cages through subtle modification of the face-capping ligand
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-22T23%3A44%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Variation%20of%20guest%20selectivity%20within%20%5BFe%20sub(4)L%20sub(4)%5D%20super(8%20+)%20tetrahedral%20cages%20through%20subtle%20modification%20of%20the%20face-capping%20ligand&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Ferguson,%20Alan&rft.date=2014-09-01&rft.volume=43&rft.issue=39&rft.spage=14550&rft.epage=14553&rft.pages=14550-14553&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c4dt02337d&rft_dat=%3Cproquest%3E1744675093%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1744675093&rft_id=info:pmid/&rfr_iscdi=true