Efficient two directional syntheses of a homophthalate ester and novel resorcylate oligomers

Thermolysis of 6,6′-(2-oxopropane-1,3-diyl)bis(2,2-dimethyl-4 H-1,3-dioxin-4-one) in the presence of methanol gave a triketo-ester which subsequently aromatized to provide a synthetically useful homophthalate ester. Enolate C-acylation in the presence of diethylzinc was used to synthesize other doub...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Tetrahedron letters 2011-04, Vol.52 (17), p.2258-2261
Hauptverfasser:	Patel, Bhavesh H., Heath, Scott F.A., Mason, Andrew M., Barrett, Anthony G.M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatization Chemistry Derivatives Double dioxinone Esters Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Homophthalate ester Methyl alcohol Noncondensed benzenic compounds Oligomers Organic chemistry Preparations and properties Resorcylate Ring opening Tetrahedrons
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Thermolysis of 6,6′-(2-oxopropane-1,3-diyl)bis(2,2-dimethyl-4 H-1,3-dioxin-4-one) in the presence of methanol gave a triketo-ester which subsequently aromatized to provide a synthetically useful homophthalate ester. Enolate C-acylation in the presence of diethylzinc was used to synthesize other double diketo-dioxinones, which on cyclization, aromatization and dioxinone ring opening gave novel double resorcylate derivatives.
ISSN:	0040-4039 1873-3581
DOI:	10.1016/j.tetlet.2011.01.100