Triplet halocarbene chemistry: p-nitrophenylchlorocarbene and p-nitrophenylbromocarbene

Reactions of p-nitrophenylchlorocarbene with cumene and of p-nitrophenylbromocarbene with toluene afford C–H abstraction–recombination products that suggest the involvement of triplet arylhalocarbenes. Reactions of p-nitrophenylchlorocarbene with cumene and of p-nitrophenylbromocarbene with toluene...

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Veröffentlicht in:Tetrahedron letters 2010-11, Vol.51 (45), p.5940-5942
Hauptverfasser: Moss, Robert A., Lu, Zhifeng, Sauers, Ronald R.
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container_title Tetrahedron letters
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creator Moss, Robert A.
Lu, Zhifeng
Sauers, Ronald R.
description Reactions of p-nitrophenylchlorocarbene with cumene and of p-nitrophenylbromocarbene with toluene afford C–H abstraction–recombination products that suggest the involvement of triplet arylhalocarbenes. Reactions of p-nitrophenylchlorocarbene with cumene and of p-nitrophenylbromocarbene with toluene afford C–H abstraction–recombination products that suggest the involvement of triplet arylhalocarbenes.
doi_str_mv 10.1016/j.tetlet.2010.09.018
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subjects Carbenes
Cumene
H-abstraction
Radicals
Tetrahedrons
Toluene
Triplets
title Triplet halocarbene chemistry: p-nitrophenylchlorocarbene and p-nitrophenylbromocarbene
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