In air a spin crossover active iron(II) complex of amine/NCBH3(-) ligands is converted to a low spin complex of imine/CN(-) ligands

Two new mononuclear Fe(II) complexes, [FeL1(NCBH3)2] (1) and [FeL2(CN)2]·3H2O (2) (L1 = N,N'-bis(2-pyridylmethyl)-1,2-ethanediamine, L2 = N-(2-pyridylmethyl)-N'-(2-pyridylmethylene)-1,2-ethanediamine) were synthesized from the same starting solution under different atmospheric conditions....

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2015-12, Vol.44 (47), p.20551-20561
Hauptverfasser:	Zhou, Jian, Zhu, Bo-Wen, Luan, Jie, Liu, Zhan, Fang, Jing-Kun, Bao, Xin, Peng, Guo, Tucek, Jiri, Bao, Song-Song, Zheng, Li-Min
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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