Straightforward synthesis and catalytic applications of rigid N,O-type calixarene ligands

Here, we report a simple one-step access to new rigid N,O-calixarene ligands which is based on copper-catalyzed amination at the lower rim. We also present the coordination properties of these ligands with some main group and transition metals leading to new complexes with superior catalytic activit...

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Veröffentlicht in:Organic & biomolecular chemistry 2015-01, Vol.13 (46), p.11189-11193
Hauptverfasser: Rawat, Varun, Press, Konstantin, Goldberg, Israel, Vigalok, Arkadi
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container_title Organic & biomolecular chemistry
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creator Rawat, Varun
Press, Konstantin
Goldberg, Israel
Vigalok, Arkadi
description Here, we report a simple one-step access to new rigid N,O-calixarene ligands which is based on copper-catalyzed amination at the lower rim. We also present the coordination properties of these ligands with some main group and transition metals leading to new complexes with superior catalytic activity, in several organic transformations, compared with calixarene metal complexes reported in the literature.
doi_str_mv 10.1039/c5ob01987g
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Straightforward synthesis and catalytic applications of rigid N,O-type calixarene ligands
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