One-Dimensional [P15]− Tubes in Layered Semiconducting AgP15

One-Dimensional [P15]− Tubes in Layered Semiconducting AgP15

AgP15 was synthesized from the elements via a short-way transport reaction following the mineralizer concept. The needle-shaped crystals were characterized by single-crystal and powder X-ray diffraction. It crystallizes triclinically in space group P1̅ with cell parameters of a = 6.937(1) Å, b = 9.0...

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Veröffentlicht in:Inorganic chemistry 2015-11, Vol.54 (22), p.10794-10800
Hauptverfasser: Grotz, Carolin, Schäfer, Konrad, Baumgartner, Maximilian, Weihrich, Richard, Nilges, Tom
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container_issue 22
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container_title Inorganic chemistry
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creator Grotz, Carolin
Schäfer, Konrad
Baumgartner, Maximilian
Weihrich, Richard
Nilges, Tom
description AgP15 was synthesized from the elements via a short-way transport reaction following the mineralizer concept. The needle-shaped crystals were characterized by single-crystal and powder X-ray diffraction. It crystallizes triclinically in space group P1̅ with cell parameters of a = 6.937(1) Å, b = 9.000(1) Å, c = 11.103(2) Å, α = 99.95(1)°, β = 99.61(1)°, and γ = 105.980(9)°. AgP15 exhibits a tubular phosphorus substructure related but neither isotypic nor isostructural to the alkaline phosphides MP15 (M = Li–Rb). The thermal properties, electronic structure, and experimental band gap of this new semiconductor have been determined. Finally, Raman spectra of AgP15 and selected alkaline-metal polyphosphides MP15 have been measured and interpreted. AgP15 represents the first transition-metal representative of this class of materials.
doi_str_mv 10.1021/acs.inorgchem.5b01856
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