Photoelectron spectroscopic and computational study of (M-CO2)(-) anions, M = Cu, Ag, Au
In a combined photoelectron spectroscopic and computational study of (M-CO2)(-), M = Au, Ag, Cu, anionic complexes, we show that (Au-CO2)(-) forms both the chemisorbed and physisorbed isomers, AuCO2(-) and Au(-)(CO2), respectively; that (Ag-CO2)(-) forms only the physisorbed isomer, Ag(-)(CO2); and...
Gespeichert in:
| Veröffentlicht in: | The Journal of chemical physics 2015-11, Vol.143 (17), p.174305-174305 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 174305 |
|---|---|
| container_issue | 17 |
| container_start_page | 174305 |
| container_title | The Journal of chemical physics |
| container_volume | 143 |
| creator | Zhang, Xinxing Lim, Eunhak Kim, Seong K Bowen, Kit H |
| description | In a combined photoelectron spectroscopic and computational study of (M-CO2)(-), M = Au, Ag, Cu, anionic complexes, we show that (Au-CO2)(-) forms both the chemisorbed and physisorbed isomers, AuCO2(-) and Au(-)(CO2), respectively; that (Ag-CO2)(-) forms only the physisorbed isomer, Ag(-)(CO2); and that (Cu-CO2)(-) forms only the chemisorbed isomer, CuCO2(-). The two chemisorbed complexes, AuCO2(-) and CuCO2(-), are covalently bound, formate-like anions, in which their CO2 moieties are significantly reduced. These two species are examples of electron-induced CO2 activation. The two physisorbed complexes, Au(-)(CO2) and Ag(-)(CO2), are electrostatically and thus weakly bound. |
| doi_str_mv | 10.1063/1.4935061 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1732307061</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1732307061</sourcerecordid><originalsourceid>FETCH-LOGICAL-c379t-f7b3931377eff6e526d8a5443bc4092cf5244c3caf28cb8c0421bf95ae9ac6193</originalsourceid><addsrcrecordid>eNpdkE1LAzEQhoMotlYP_gEJeGmhWzNJNtkcPJTFL2ipBwVvSzZNtGXbrJvdQ_-90VYPHoYZeB9emAehSyATIILdwIQrlhIBR6gPJFOJFIocoz4hFBIliOihsxDWhBCQlJ-iHhUplyCyPnp7_vCtt5U1beO3ONQ_RzC-Xhmst0ts_KbuWt2u_FZXOLTdcoe9w8N5ki_oaJiMIhWzMMZzfIvzboyn73G6c3TidBXsxWEP0Ov93Uv-mMwWD0_5dJYYJlWbOFkyxYBJaZ0TNqVimemUc1YaThQ1LqWcG2a0o5kpM0M4hdKpVFuljQDFBmi4760b_9nZ0BabVTC2qvTW-i4UIBllREY5Eb3-h65918S3QkGBsgyA0CxSoz1loofQWFfUzWqjm10BpPjWXUBx0B3Zq0NjV27s8o_89cu-AE5bdfU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2123811028</pqid></control><display><type>article</type><title>Photoelectron spectroscopic and computational study of (M-CO2)(-) anions, M = Cu, Ag, Au</title><source>AIP Journals Complete</source><source>Alma/SFX Local Collection</source><creator>Zhang, Xinxing ; Lim, Eunhak ; Kim, Seong K ; Bowen, Kit H</creator><creatorcontrib>Zhang, Xinxing ; Lim, Eunhak ; Kim, Seong K ; Bowen, Kit H</creatorcontrib><description>In a combined photoelectron spectroscopic and computational study of (M-CO2)(-), M = Au, Ag, Cu, anionic complexes, we show that (Au-CO2)(-) forms both the chemisorbed and physisorbed isomers, AuCO2(-) and Au(-)(CO2), respectively; that (Ag-CO2)(-) forms only the physisorbed isomer, Ag(-)(CO2); and that (Cu-CO2)(-) forms only the chemisorbed isomer, CuCO2(-). The two chemisorbed complexes, AuCO2(-) and CuCO2(-), are covalently bound, formate-like anions, in which their CO2 moieties are significantly reduced. These two species are examples of electron-induced CO2 activation. The two physisorbed complexes, Au(-)(CO2) and Ag(-)(CO2), are electrostatically and thus weakly bound.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.4935061</identifier><identifier>PMID: 26547168</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>Anions ; Carbon dioxide ; Computation ; Copper ; Gold ; Isomers ; Organic chemistry ; Physics ; Silver ; Spectroscopic analysis</subject><ispartof>The Journal of chemical physics, 2015-11, Vol.143 (17), p.174305-174305</ispartof><rights>2015 AIP Publishing LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c379t-f7b3931377eff6e526d8a5443bc4092cf5244c3caf28cb8c0421bf95ae9ac6193</citedby><cites>FETCH-LOGICAL-c379t-f7b3931377eff6e526d8a5443bc4092cf5244c3caf28cb8c0421bf95ae9ac6193</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26547168$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Xinxing</creatorcontrib><creatorcontrib>Lim, Eunhak</creatorcontrib><creatorcontrib>Kim, Seong K</creatorcontrib><creatorcontrib>Bowen, Kit H</creatorcontrib><title>Photoelectron spectroscopic and computational study of (M-CO2)(-) anions, M = Cu, Ag, Au</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>In a combined photoelectron spectroscopic and computational study of (M-CO2)(-), M = Au, Ag, Cu, anionic complexes, we show that (Au-CO2)(-) forms both the chemisorbed and physisorbed isomers, AuCO2(-) and Au(-)(CO2), respectively; that (Ag-CO2)(-) forms only the physisorbed isomer, Ag(-)(CO2); and that (Cu-CO2)(-) forms only the chemisorbed isomer, CuCO2(-). The two chemisorbed complexes, AuCO2(-) and CuCO2(-), are covalently bound, formate-like anions, in which their CO2 moieties are significantly reduced. These two species are examples of electron-induced CO2 activation. The two physisorbed complexes, Au(-)(CO2) and Ag(-)(CO2), are electrostatically and thus weakly bound.</description><subject>Anions</subject><subject>Carbon dioxide</subject><subject>Computation</subject><subject>Copper</subject><subject>Gold</subject><subject>Isomers</subject><subject>Organic chemistry</subject><subject>Physics</subject><subject>Silver</subject><subject>Spectroscopic analysis</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpdkE1LAzEQhoMotlYP_gEJeGmhWzNJNtkcPJTFL2ipBwVvSzZNtGXbrJvdQ_-90VYPHoYZeB9emAehSyATIILdwIQrlhIBR6gPJFOJFIocoz4hFBIliOihsxDWhBCQlJ-iHhUplyCyPnp7_vCtt5U1beO3ONQ_RzC-Xhmst0ts_KbuWt2u_FZXOLTdcoe9w8N5ki_oaJiMIhWzMMZzfIvzboyn73G6c3TidBXsxWEP0Ov93Uv-mMwWD0_5dJYYJlWbOFkyxYBJaZ0TNqVimemUc1YaThQ1LqWcG2a0o5kpM0M4hdKpVFuljQDFBmi4760b_9nZ0BabVTC2qvTW-i4UIBllREY5Eb3-h65918S3QkGBsgyA0CxSoz1loofQWFfUzWqjm10BpPjWXUBx0B3Zq0NjV27s8o_89cu-AE5bdfU</recordid><startdate>20151107</startdate><enddate>20151107</enddate><creator>Zhang, Xinxing</creator><creator>Lim, Eunhak</creator><creator>Kim, Seong K</creator><creator>Bowen, Kit H</creator><general>American Institute of Physics</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20151107</creationdate><title>Photoelectron spectroscopic and computational study of (M-CO2)(-) anions, M = Cu, Ag, Au</title><author>Zhang, Xinxing ; Lim, Eunhak ; Kim, Seong K ; Bowen, Kit H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c379t-f7b3931377eff6e526d8a5443bc4092cf5244c3caf28cb8c0421bf95ae9ac6193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Anions</topic><topic>Carbon dioxide</topic><topic>Computation</topic><topic>Copper</topic><topic>Gold</topic><topic>Isomers</topic><topic>Organic chemistry</topic><topic>Physics</topic><topic>Silver</topic><topic>Spectroscopic analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xinxing</creatorcontrib><creatorcontrib>Lim, Eunhak</creatorcontrib><creatorcontrib>Kim, Seong K</creatorcontrib><creatorcontrib>Bowen, Kit H</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xinxing</au><au>Lim, Eunhak</au><au>Kim, Seong K</au><au>Bowen, Kit H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoelectron spectroscopic and computational study of (M-CO2)(-) anions, M = Cu, Ag, Au</atitle><jtitle>The Journal of chemical physics</jtitle><addtitle>J Chem Phys</addtitle><date>2015-11-07</date><risdate>2015</risdate><volume>143</volume><issue>17</issue><spage>174305</spage><epage>174305</epage><pages>174305-174305</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>In a combined photoelectron spectroscopic and computational study of (M-CO2)(-), M = Au, Ag, Cu, anionic complexes, we show that (Au-CO2)(-) forms both the chemisorbed and physisorbed isomers, AuCO2(-) and Au(-)(CO2), respectively; that (Ag-CO2)(-) forms only the physisorbed isomer, Ag(-)(CO2); and that (Cu-CO2)(-) forms only the chemisorbed isomer, CuCO2(-). The two chemisorbed complexes, AuCO2(-) and CuCO2(-), are covalently bound, formate-like anions, in which their CO2 moieties are significantly reduced. These two species are examples of electron-induced CO2 activation. The two physisorbed complexes, Au(-)(CO2) and Ag(-)(CO2), are electrostatically and thus weakly bound.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><pmid>26547168</pmid><doi>10.1063/1.4935061</doi><tpages>1</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 2015-11, Vol.143 (17), p.174305-174305 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1732307061 |
| source | AIP Journals Complete; Alma/SFX Local Collection |
| subjects | Anions Carbon dioxide Computation Copper Gold Isomers Organic chemistry Physics Silver Spectroscopic analysis |
| title | Photoelectron spectroscopic and computational study of (M-CO2)(-) anions, M = Cu, Ag, Au |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-21T01%3A31%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photoelectron%20spectroscopic%20and%20computational%20study%20of%20(M-CO2)(-)%20anions,%20M%20=%20Cu,%20Ag,%20Au&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Zhang,%20Xinxing&rft.date=2015-11-07&rft.volume=143&rft.issue=17&rft.spage=174305&rft.epage=174305&rft.pages=174305-174305&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.4935061&rft_dat=%3Cproquest_cross%3E1732307061%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2123811028&rft_id=info:pmid/26547168&rfr_iscdi=true |