Polytypism and oxo-tungstate polyhedra polymerization in novel complex uranyl tungstates
Three new uranyl tungstates, α-, β-Cs(2)[(UO(2))(2)(W(2)O(9))], and Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)], have been obtained by high temperature solid state reactions. All three compounds display novel structure topologies: α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] are based upon layers with a new...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2012-07, Vol.41 (28), p.8512-8514 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 8514 |
|---|---|
| container_issue | 28 |
| container_start_page | 8512 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 41 |
| creator | Seliverstov, Andrey N Suleimanov, Evgeny V Chuprunov, Evgeny V Somov, Nikolay V Zhuchkova, Elena M Lelet, Maxim I Rozov, Konstantin B Depmeier, Wulf Krivovichev, Sergey V Alekseev, Evgeny V |
| description | Three new uranyl tungstates, α-, β-Cs(2)[(UO(2))(2)(W(2)O(9))], and Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)], have been obtained by high temperature solid state reactions. All three compounds display novel structure topologies: α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] are based upon layers with a new topology that can be related to the uranophane topology; Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)] is a rare example of a non-molecular inorganic phase with layers containing oxo-tungstate trimers. The structural relationship between α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] can be assigned to polytypism. |
| doi_str_mv | 10.1039/c2dt31000g |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1730112130</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1022852936</sourcerecordid><originalsourceid>FETCH-LOGICAL-c389t-62a3cc6f5a066e3cdab37c0fd1bcffff451797b4362b70597ba4c03a9810be053</originalsourceid><addsrcrecordid>eNqNkU9LxDAQxYMo7rp68QNIjiJUJ0mbNEdZ_AeCHhS8lTRN10rb1CSVrZ_erruuR53LPJjfvMN7CB0TOCfA5IWmRWAEABY7aEpiISJJWby71ZRP0IH3bwCUQkL30YRSQUAmMEUvj7YewtBVvsGqLbBd2ij07cIHFQzuxuOrKZz6Vo1x1acKlW1x1eLWfpgaa9t0tVni3ql2qPH21R-ivVLV3hxt9gw9X189zW-j-4ebu_nlfaRZKkPEqWJa8zJRwLlhulA5ExrKguS6HCdOiJAijxmnuYBklCrWwJRMCeQGEjZDp2vfztn33viQNZXXpq5Va2zvMyIYEEIJg79RSFcB8VT8A6U0TahkfETP1qh21ntnyqxzVaPcMELZqp_st58RPtn49nljii36Uwj7AltIjIs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1022852936</pqid></control><display><type>article</type><title>Polytypism and oxo-tungstate polyhedra polymerization in novel complex uranyl tungstates</title><source>MEDLINE</source><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Seliverstov, Andrey N ; Suleimanov, Evgeny V ; Chuprunov, Evgeny V ; Somov, Nikolay V ; Zhuchkova, Elena M ; Lelet, Maxim I ; Rozov, Konstantin B ; Depmeier, Wulf ; Krivovichev, Sergey V ; Alekseev, Evgeny V</creator><creatorcontrib>Seliverstov, Andrey N ; Suleimanov, Evgeny V ; Chuprunov, Evgeny V ; Somov, Nikolay V ; Zhuchkova, Elena M ; Lelet, Maxim I ; Rozov, Konstantin B ; Depmeier, Wulf ; Krivovichev, Sergey V ; Alekseev, Evgeny V</creatorcontrib><description>Three new uranyl tungstates, α-, β-Cs(2)[(UO(2))(2)(W(2)O(9))], and Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)], have been obtained by high temperature solid state reactions. All three compounds display novel structure topologies: α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] are based upon layers with a new topology that can be related to the uranophane topology; Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)] is a rare example of a non-molecular inorganic phase with layers containing oxo-tungstate trimers. The structural relationship between α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] can be assigned to polytypism.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c2dt31000g</identifier><identifier>PMID: 22710950</identifier><language>eng</language><publisher>England</publisher><subject>Molecular Structure ; Polyhedra ; Polyhedrons ; Polymerization ; Solid state ; Topology ; Trimers ; Tungstates ; Tungsten Compounds - chemical synthesis ; Tungsten Compounds - chemistry ; Uranium Compounds - chemical synthesis ; Uranium Compounds - chemistry</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2012-07, Vol.41 (28), p.8512-8514</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-62a3cc6f5a066e3cdab37c0fd1bcffff451797b4362b70597ba4c03a9810be053</citedby><cites>FETCH-LOGICAL-c389t-62a3cc6f5a066e3cdab37c0fd1bcffff451797b4362b70597ba4c03a9810be053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27911,27912</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22710950$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Seliverstov, Andrey N</creatorcontrib><creatorcontrib>Suleimanov, Evgeny V</creatorcontrib><creatorcontrib>Chuprunov, Evgeny V</creatorcontrib><creatorcontrib>Somov, Nikolay V</creatorcontrib><creatorcontrib>Zhuchkova, Elena M</creatorcontrib><creatorcontrib>Lelet, Maxim I</creatorcontrib><creatorcontrib>Rozov, Konstantin B</creatorcontrib><creatorcontrib>Depmeier, Wulf</creatorcontrib><creatorcontrib>Krivovichev, Sergey V</creatorcontrib><creatorcontrib>Alekseev, Evgeny V</creatorcontrib><title>Polytypism and oxo-tungstate polyhedra polymerization in novel complex uranyl tungstates</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Three new uranyl tungstates, α-, β-Cs(2)[(UO(2))(2)(W(2)O(9))], and Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)], have been obtained by high temperature solid state reactions. All three compounds display novel structure topologies: α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] are based upon layers with a new topology that can be related to the uranophane topology; Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)] is a rare example of a non-molecular inorganic phase with layers containing oxo-tungstate trimers. The structural relationship between α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] can be assigned to polytypism.</description><subject>Molecular Structure</subject><subject>Polyhedra</subject><subject>Polyhedrons</subject><subject>Polymerization</subject><subject>Solid state</subject><subject>Topology</subject><subject>Trimers</subject><subject>Tungstates</subject><subject>Tungsten Compounds - chemical synthesis</subject><subject>Tungsten Compounds - chemistry</subject><subject>Uranium Compounds - chemical synthesis</subject><subject>Uranium Compounds - chemistry</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkU9LxDAQxYMo7rp68QNIjiJUJ0mbNEdZ_AeCHhS8lTRN10rb1CSVrZ_erruuR53LPJjfvMN7CB0TOCfA5IWmRWAEABY7aEpiISJJWby71ZRP0IH3bwCUQkL30YRSQUAmMEUvj7YewtBVvsGqLbBd2ij07cIHFQzuxuOrKZz6Vo1x1acKlW1x1eLWfpgaa9t0tVni3ql2qPH21R-ivVLV3hxt9gw9X189zW-j-4ebu_nlfaRZKkPEqWJa8zJRwLlhulA5ExrKguS6HCdOiJAijxmnuYBklCrWwJRMCeQGEjZDp2vfztn33viQNZXXpq5Va2zvMyIYEEIJg79RSFcB8VT8A6U0TahkfETP1qh21ntnyqxzVaPcMELZqp_st58RPtn49nljii36Uwj7AltIjIs</recordid><startdate>20120728</startdate><enddate>20120728</enddate><creator>Seliverstov, Andrey N</creator><creator>Suleimanov, Evgeny V</creator><creator>Chuprunov, Evgeny V</creator><creator>Somov, Nikolay V</creator><creator>Zhuchkova, Elena M</creator><creator>Lelet, Maxim I</creator><creator>Rozov, Konstantin B</creator><creator>Depmeier, Wulf</creator><creator>Krivovichev, Sergey V</creator><creator>Alekseev, Evgeny V</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>7SR</scope><scope>8BQ</scope><scope>JG9</scope></search><sort><creationdate>20120728</creationdate><title>Polytypism and oxo-tungstate polyhedra polymerization in novel complex uranyl tungstates</title><author>Seliverstov, Andrey N ; Suleimanov, Evgeny V ; Chuprunov, Evgeny V ; Somov, Nikolay V ; Zhuchkova, Elena M ; Lelet, Maxim I ; Rozov, Konstantin B ; Depmeier, Wulf ; Krivovichev, Sergey V ; Alekseev, Evgeny V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-62a3cc6f5a066e3cdab37c0fd1bcffff451797b4362b70597ba4c03a9810be053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Molecular Structure</topic><topic>Polyhedra</topic><topic>Polyhedrons</topic><topic>Polymerization</topic><topic>Solid state</topic><topic>Topology</topic><topic>Trimers</topic><topic>Tungstates</topic><topic>Tungsten Compounds - chemical synthesis</topic><topic>Tungsten Compounds - chemistry</topic><topic>Uranium Compounds - chemical synthesis</topic><topic>Uranium Compounds - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Seliverstov, Andrey N</creatorcontrib><creatorcontrib>Suleimanov, Evgeny V</creatorcontrib><creatorcontrib>Chuprunov, Evgeny V</creatorcontrib><creatorcontrib>Somov, Nikolay V</creatorcontrib><creatorcontrib>Zhuchkova, Elena M</creatorcontrib><creatorcontrib>Lelet, Maxim I</creatorcontrib><creatorcontrib>Rozov, Konstantin B</creatorcontrib><creatorcontrib>Depmeier, Wulf</creatorcontrib><creatorcontrib>Krivovichev, Sergey V</creatorcontrib><creatorcontrib>Alekseev, Evgeny V</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Materials Research Database</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Seliverstov, Andrey N</au><au>Suleimanov, Evgeny V</au><au>Chuprunov, Evgeny V</au><au>Somov, Nikolay V</au><au>Zhuchkova, Elena M</au><au>Lelet, Maxim I</au><au>Rozov, Konstantin B</au><au>Depmeier, Wulf</au><au>Krivovichev, Sergey V</au><au>Alekseev, Evgeny V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polytypism and oxo-tungstate polyhedra polymerization in novel complex uranyl tungstates</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2012-07-28</date><risdate>2012</risdate><volume>41</volume><issue>28</issue><spage>8512</spage><epage>8514</epage><pages>8512-8514</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Three new uranyl tungstates, α-, β-Cs(2)[(UO(2))(2)(W(2)O(9))], and Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)], have been obtained by high temperature solid state reactions. All three compounds display novel structure topologies: α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] are based upon layers with a new topology that can be related to the uranophane topology; Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)] is a rare example of a non-molecular inorganic phase with layers containing oxo-tungstate trimers. The structural relationship between α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] can be assigned to polytypism.</abstract><cop>England</cop><pmid>22710950</pmid><doi>10.1039/c2dt31000g</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2012-07, Vol.41 (28), p.8512-8514 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1730112130 |
| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Molecular Structure Polyhedra Polyhedrons Polymerization Solid state Topology Trimers Tungstates Tungsten Compounds - chemical synthesis Tungsten Compounds - chemistry Uranium Compounds - chemical synthesis Uranium Compounds - chemistry |
| title | Polytypism and oxo-tungstate polyhedra polymerization in novel complex uranyl tungstates |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T03%3A17%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polytypism%20and%20oxo-tungstate%20polyhedra%20polymerization%20in%20novel%20complex%20uranyl%20tungstates&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Seliverstov,%20Andrey%20N&rft.date=2012-07-28&rft.volume=41&rft.issue=28&rft.spage=8512&rft.epage=8514&rft.pages=8512-8514&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c2dt31000g&rft_dat=%3Cproquest_cross%3E1022852936%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1022852936&rft_id=info:pmid/22710950&rfr_iscdi=true |