Preparation and properties of a series of structurally diverse aluminium hydrides supported by β-diketiminate and bis(amide) ligands

The synthesis of a diverse series of hydride complexes of aluminium coordinated by N,N'-chelating ligands is reported. Reaction of [{2,6-(i)Pr2C6H3}NC(Me)CHC(Me)N(H)CH2CH2NMe2] with either LiAlH4 or Me3N·AlH3 allows isolation of the corresponding five-coordinate aluminium dihydride [κ(3)-{(2,6-...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2013-11, Vol.42 (42), p.15199-15206
Hauptverfasser:	Nako, Adi E, Gates, Sarah J, White, Andrew J P, Crimmin, Mark R
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminium Aluminum Diffraction Dihydrides Heating Hydrides Jewelry Ligands
Online-Zugang:	Volltext
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