Monolithic porous layer open tubular (monoPLOT) capillary columns for gas chromatography
Polymer monolithic open tubular columns are presented as a solid adsorbent for fast and efficient gas phase separations. A porous monolithic layer of polystyrene-divinylbenzene was formed inside a capillary through an in situ polymerisation method creating a long, open bore column with high flow thr...
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| Veröffentlicht in: | RSC advances 2015-01, Vol.5 (11), p.789-7896 |
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| container_title | RSC advances |
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| creator | Nesterenko, Ekaterina P Burke, Maurice de Bosset, Christophe Pessutto, Paulo Malafosse, Claire Collins, David A |
| description | Polymer monolithic open tubular columns are presented as a solid adsorbent for fast and efficient gas phase separations. A porous monolithic layer of polystyrene-divinylbenzene was formed inside a capillary through an
in situ
polymerisation method creating a long, open bore column with high flow through permeability. The mechanical stability and chromatographic performance of the column was tested, showing the phase to be extremely stable up to 270 °C and capable of fast separations with efficiencies of almost 4000 theoretical plates per meter.
Polymer monolithic open tubular columns are presented as a solid adsorbent for fast and efficient gas phase separations. |
| doi_str_mv | 10.1039/c4ra13498b |
| format | Article |
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in situ
polymerisation method creating a long, open bore column with high flow through permeability. The mechanical stability and chromatographic performance of the column was tested, showing the phase to be extremely stable up to 270 °C and capable of fast separations with efficiencies of almost 4000 theoretical plates per meter.
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in situ
polymerisation method creating a long, open bore column with high flow through permeability. The mechanical stability and chromatographic performance of the column was tested, showing the phase to be extremely stable up to 270 °C and capable of fast separations with efficiencies of almost 4000 theoretical plates per meter.
Polymer monolithic open tubular columns are presented as a solid adsorbent for fast and efficient gas phase separations.</description><subject>Adsorbents</subject><subject>Capillarity</subject><subject>Chromatography</subject><subject>Gas phases</subject><subject>Measuring instruments</subject><subject>Permeability</subject><subject>Separation</subject><subject>Stability</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kM1LAzEQxYMoWLQX70K8VWE12aRp9liLX1CpSAVvy-w0aVd2N2uye-h_b7SinpzLDDM_hvceISecXXImsiuUHriQmS72yCBlUiUpU9n-n_mQDEN4Y7HUmKeKD8jro2tcVXabEmnrvOsDrWBrPHWtaWjXF30Fno7qSD3NF8tzitCWVdxtKbqqr5tArfN0DYHixrsaOrf20G62x-TAQhXM8LsfkZfbm-XsPpkv7h5m03mCgqddIifaZrLADAHYigtuhbZCyqiOgZHSCi5TUxQIKVpIDYzjotCF1kaNkaM4IqPd39a7996ELq_LgCZKbEx0k_OJYJxpNVERvdih6F0I3ti89WUdreSc5Z8J5jP5PP1K8DrCpzvYB_zhfhOO97P_7nm7suIDtPN5nQ</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Nesterenko, Ekaterina P</creator><creator>Burke, Maurice</creator><creator>de Bosset, Christophe</creator><creator>Pessutto, Paulo</creator><creator>Malafosse, Claire</creator><creator>Collins, David A</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20150101</creationdate><title>Monolithic porous layer open tubular (monoPLOT) capillary columns for gas chromatography</title><author>Nesterenko, Ekaterina P ; Burke, Maurice ; de Bosset, Christophe ; Pessutto, Paulo ; Malafosse, Claire ; Collins, David A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c312t-478f94bc9caa0d131f38f3441260ae44f3142ebbca2cfa2ea5314b8b88e65c1c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Adsorbents</topic><topic>Capillarity</topic><topic>Chromatography</topic><topic>Gas phases</topic><topic>Measuring instruments</topic><topic>Permeability</topic><topic>Separation</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nesterenko, Ekaterina P</creatorcontrib><creatorcontrib>Burke, Maurice</creatorcontrib><creatorcontrib>de Bosset, Christophe</creatorcontrib><creatorcontrib>Pessutto, Paulo</creatorcontrib><creatorcontrib>Malafosse, Claire</creatorcontrib><creatorcontrib>Collins, David A</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nesterenko, Ekaterina P</au><au>Burke, Maurice</au><au>de Bosset, Christophe</au><au>Pessutto, Paulo</au><au>Malafosse, Claire</au><au>Collins, David A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Monolithic porous layer open tubular (monoPLOT) capillary columns for gas chromatography</atitle><jtitle>RSC advances</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>5</volume><issue>11</issue><spage>789</spage><epage>7896</epage><pages>789-7896</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Polymer monolithic open tubular columns are presented as a solid adsorbent for fast and efficient gas phase separations. A porous monolithic layer of polystyrene-divinylbenzene was formed inside a capillary through an
in situ
polymerisation method creating a long, open bore column with high flow through permeability. The mechanical stability and chromatographic performance of the column was tested, showing the phase to be extremely stable up to 270 °C and capable of fast separations with efficiencies of almost 4000 theoretical plates per meter.
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| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2015-01, Vol.5 (11), p.789-7896 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1730108676 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Adsorbents Capillarity Chromatography Gas phases Measuring instruments Permeability Separation Stability |
| title | Monolithic porous layer open tubular (monoPLOT) capillary columns for gas chromatography |
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