Ruthenium amino carboxylate complexes as asymmetric hydrogen transfer catalysts

The synthesis and characterization of optically active amino carboxylate complexes of formula [(η(6)-arene)Ru(Aa)Cl] (arene = C(6)H(6), C(6)Me(6), Aa = amino carboxylate) as well as those of the related trimers [{(η(6)-arene)Ru(Aa)}(3)][BF(4)](3) are reported. Trimerization takes place with chiral s...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2012-09, Vol.41 (34), p.10298-10308
Hauptverfasser:	Carmona, Daniel, Viguri, Fernando, Pilar Lamata, M, Ferrer, Joaquina, Bardají, Elisa, Lahoz, Fernando J, García-Orduña, Pilar, Oro, Luis A
Format:	Artikel
Sprache:	eng
Schlagworte:	2-Propanol - chemistry Asymmetry Carboxylates Carboxylic Acids - chemistry Catalysis Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Crystal structure Crystallography, X-Ray Diffraction Hydrogen - chemistry Ketones - chemistry Molecular Conformation Optical activity Ruthenium Ruthenium - chemistry Trimers X-rays
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