Doubly TEMPO-coordinated gadolinium(III), lanthanum(III), and yttrium(III) complexes. Strong superexchange coupling across rare earth ions

We prepared crystalline [RE(III)(hfac)3(TEMPO)2] (RE = Gd, La, Y), where TEMPO and hfac stand for 2,2,6,6-tetramethylpiperidin-1-oxyl and 1,1,1,5,5,5-hexafluoropentane-2,4-dionate, respectively. The X-ray crystal structure of TEMPO-coordinated RE compounds was determined for the first time. The Gd a...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-04, Vol.43 (15), p.5893-5898
Hauptverfasser:	Murakami, Rina, Nakamura, Takeshi, Ishida, Takayuki
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Couplings Crystal structure Derivatives Exchange Ion exchangers Rare earth metals Stands
Online-Zugang:	Volltext
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