Indium( iii )-catalyzed tandem synthesis of 2-alkynyl-3,3-dichloropyrrolidines and their conversion to 3-chloropyrroles

The synthetic utility of electron-deficient α,α,γ-trichloroaldimines was demonstrated by an indium( iii ) triflate-catalyzed cascade reaction with terminal alkynes allowing one to rapidly and selectively access 2-alkynyl-3,3-dichloropyrrolidines in good to excellent yields. The reaction proceeds in...

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Veröffentlicht in:	RSC advances 2015, Vol.5 (14), p.10139-10151
Hauptverfasser:	Kushwaha, Khushbu, Malakar, C. C., Stas, S., Lemière, F., Abbaspour Tehrani, Kourosch
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Aromatic compounds Conversion Imines Synthesis Terminals Transformations Utilities
Online-Zugang:	Volltext
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