Structural, electrical and luminescent properties of ZnO:Li films fabricated by screen-printing method on sapphire substrate

Undoped and Li‐doped ZnO thick films were fabricated by a screen‐printing technique on sapphire substrate. The effect of sintering temperature (TS = 800, 900 and 1000 °C) and Li content ([Li] = 0.003, 0.03 and 0.3 wt%) on the photoluminescence (PL), electrical and structural properties of the films...

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Veröffentlicht in:Physica status solidi. C 2015-08, Vol.12 (8), p.1144-1147
Hauptverfasser: Khomenkova, L., Kushnirenko, V. I., Osipyonok, M. M., Syngaivsky, O. F., Zashivailo, T. V., Pekar, G. S., Polishchuk, Yu. O., Kladko, V. P., Borkovska, L. V.
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container_issue 8
container_start_page 1144
container_title Physica status solidi. C
container_volume 12
creator Khomenkova, L.
Kushnirenko, V. I.
Osipyonok, M. M.
Syngaivsky, O. F.
Zashivailo, T. V.
Pekar, G. S.
Polishchuk, Yu. O.
Kladko, V. P.
Borkovska, L. V.
description Undoped and Li‐doped ZnO thick films were fabricated by a screen‐printing technique on sapphire substrate. The effect of sintering temperature (TS = 800, 900 and 1000 °C) and Li content ([Li] = 0.003, 0.03 and 0.3 wt%) on the photoluminescence (PL), electrical and structural properties of the films was investigated. The X‐ray diffraction shows that all the films are polycrystalline with a wurtzite structure. It is found that both high sintering temperature and low Li content favour formation of the low‐resistive films with an enhanced UV emission. The high Li content stimulates an appearance of semi‐insulating behaviour of the films and deteriorated PL properties. It is shown that the effect of Li‐doping on light‐emitting properties of the films consists mainly in the modification of the film crystallinity and the engineering of the concentration of intrinsic defects. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
doi_str_mv 10.1002/pssc.201400232
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subjects Crystal defects
defects
Diffraction
Li doping
Lithium
photoluminescence
Sapphire
screen-printed films
Sintering
Solid state physics
Thick films
Wurtzite
XRD
zinc oxide
title Structural, electrical and luminescent properties of ZnO:Li films fabricated by screen-printing method on sapphire substrate
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