Enforcement of a high-spin ground state for the first 3d heterometallic 12-metallacrown-4 complex

Cu(II)(DMF)2Cl2[12-MC(Fe(III)N(Shi))-4](DMF)4·2DMF was synthesized as the first heterometallic transition metal 12-MC-4 complex. The purposeful placement of specific metal ions in the different sites of the metallacrown attains the establishment of a high-spin ground state. Inducing the anticipated...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-11, Vol.43 (41), p.15308-15312
Hauptverfasser:	Happ, Peter, Rentschler, Eva
Format:	Artikel
Sprache:	eng
Schlagworte:	Cancellation Ground state Ion exchangers Metal ions Placement Transition metals
Online-Zugang:	Volltext
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