Nano alumina–zirconia blended epoxy polymeric composites for anticorrosive applications
Amorphous alumina–zirconia (Al 2 O 3 –ZrO 2 ) nanoparticles were produced by hot-air spray pyrolysis method. Two and six layers of anticorrosive coating of epoxy polyamide (EP) resin and mixture of amorphous Al 2 O 3 –ZrO 2 nanoparticles in epoxy polyamide resin (NEP), respectively, were applied on...
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| Veröffentlicht in: | Journal of sol-gel science and technology 2015-05, Vol.74 (2), p.460-471 |
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| creator | Karthik, A. Arunmetha, S. Srither, S. R. Manivasakan, P. Rajendran, V. |
| description | Amorphous alumina–zirconia (Al
2
O
3
–ZrO
2
) nanoparticles were produced by hot-air spray pyrolysis method. Two and six layers of anticorrosive coating of epoxy polyamide (EP) resin and mixture of amorphous Al
2
O
3
–ZrO
2
nanoparticles in epoxy polyamide resin (NEP), respectively, were applied on SS 316L specimens. The performance of EP and NEP coated samples was comprehensively characterized. The results show that the sample with six layers of NEP coating (SSNEP6) has enhanced thermal, elastic properties and chemical resistance than that with six layers of EP coating (SSEP6). Thermo gravimetric analysis reveals that EP sample decomposed at 523 °C whereas NEP sample has extended thermal stability up to 750 °C with minimum residual mass. The thermal conductivity of EP sample is 0.124 while for NEP is about 0.263 W/mK. The hardness and reduced elastic modulus of SSNEP6 sample were, respectively, 318.32 MPa and 5.98 GPa whereas those of SSEP6 sample were 233.69 MPa and 4.17 GPa. Further, in-situ scanning probe microscopy (SPM)-nanoindentation and atomic force microscopy (AFM) images were obtained to explore the formation of Al
2
O
3
–ZrO
2
nano filler in EP matrix. The samples coated with multilayers of EP and NEP was exposed to acid immersion (10 % of H
2
SO
4
) for 48 h. The SPM and AFM microstructure images show that the NEP coated sample maintains its original surface feature with existing passive layer formation, whereas EP coated sample shows surface deterioration and deformation. In addition, stability of EP and NEP coated samples was measured in terms of surface roughness with respect to nano filler in epoxy matrix. This observation shows that Al
2
O
3
–ZrO
2
nanofiller can be used to improve the desirable properties in host epoxy matrix. |
| doi_str_mv | 10.1007/s10971-015-3621-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1730078127</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1730078127</sourcerecordid><originalsourceid>FETCH-LOGICAL-c419t-546f9b4f096021d54c2da620f02c5cfbf976b7477dc546628748bb1555d0d5853</originalsourceid><addsrcrecordid>eNp1kMtKxDAUhoMoOF4ewF3BjZvqOWnStEsZvIHoRheuQpqmkqFNatIRx5Xv4Bv6JGYYQRBcHTh8_885HyFHCKcIIM4iQi0wB-R5UVLMqy0yQy6KnFWs3CYzqGmVgwCxS_ZiXAAAZyhm5OlOOZ-pfjlYp74-Pt9t0N5ZlTW9ca1pMzP6t1U2-n41mGB1pv0w-mgnE7POh0y5yWofQlq9mkyNY2-1mqx38YDsdKqP5vBn7pPHy4uH-XV-e391Mz-_zTXDeso5K7u6YR3UJVBsOdO0VSWFDqjmumu6WpSNYEK0OqElrQSrmgY55y20vOLFPjnZ9I7BvyxNnORgozZ9r5zxyyhRFElQhVQk9PgPuvDL4NJ1klJe8wIZrgtxQ-n0VQymk2OwgworiSDXsuVGtkyy5Vq2rFKGbjIxse7ZhN_m_0PfeUWDIw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259531415</pqid></control><display><type>article</type><title>Nano alumina–zirconia blended epoxy polymeric composites for anticorrosive applications</title><source>SpringerLink Journals - AutoHoldings</source><creator>Karthik, A. ; Arunmetha, S. ; Srither, S. R. ; Manivasakan, P. ; Rajendran, V.</creator><creatorcontrib>Karthik, A. ; Arunmetha, S. ; Srither, S. R. ; Manivasakan, P. ; Rajendran, V.</creatorcontrib><description>Amorphous alumina–zirconia (Al
2
O
3
–ZrO
2
) nanoparticles were produced by hot-air spray pyrolysis method. Two and six layers of anticorrosive coating of epoxy polyamide (EP) resin and mixture of amorphous Al
2
O
3
–ZrO
2
nanoparticles in epoxy polyamide resin (NEP), respectively, were applied on SS 316L specimens. The performance of EP and NEP coated samples was comprehensively characterized. The results show that the sample with six layers of NEP coating (SSNEP6) has enhanced thermal, elastic properties and chemical resistance than that with six layers of EP coating (SSEP6). Thermo gravimetric analysis reveals that EP sample decomposed at 523 °C whereas NEP sample has extended thermal stability up to 750 °C with minimum residual mass. The thermal conductivity of EP sample is 0.124 while for NEP is about 0.263 W/mK. The hardness and reduced elastic modulus of SSNEP6 sample were, respectively, 318.32 MPa and 5.98 GPa whereas those of SSEP6 sample were 233.69 MPa and 4.17 GPa. Further, in-situ scanning probe microscopy (SPM)-nanoindentation and atomic force microscopy (AFM) images were obtained to explore the formation of Al
2
O
3
–ZrO
2
nano filler in EP matrix. The samples coated with multilayers of EP and NEP was exposed to acid immersion (10 % of H
2
SO
4
) for 48 h. The SPM and AFM microstructure images show that the NEP coated sample maintains its original surface feature with existing passive layer formation, whereas EP coated sample shows surface deterioration and deformation. In addition, stability of EP and NEP coated samples was measured in terms of surface roughness with respect to nano filler in epoxy matrix. This observation shows that Al
2
O
3
–ZrO
2
nanofiller can be used to improve the desirable properties in host epoxy matrix.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-015-3621-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aluminum oxide ; Atomic force microscopy ; Austenitic stainless steels ; Ceramics ; Chemistry and Materials Science ; Coating ; Composites ; Corrosion prevention ; Corrosion resistance ; Deformation ; Elastic properties ; Fillers ; Formations ; Glass ; Gravimetric analysis ; Heat resistant steels ; Inorganic Chemistry ; Materials Science ; Microscopy ; Modulus of elasticity ; Multilayers ; Nanoindentation ; Nanoparticles ; Nanostructure ; Nanotechnology ; Natural Materials ; Optical and Electronic Materials ; Organic chemistry ; Original Paper ; Polyamide resins ; Protective coatings ; Scanning probe microscopy ; Spray pyrolysis ; Submerging ; Sulfuric acid ; Surface roughness ; Surface stability ; Thermal conductivity ; Thermal stability ; Zirconium dioxide</subject><ispartof>Journal of sol-gel science and technology, 2015-05, Vol.74 (2), p.460-471</ispartof><rights>Springer Science+Business Media New York 2015</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2015). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-546f9b4f096021d54c2da620f02c5cfbf976b7477dc546628748bb1555d0d5853</citedby><cites>FETCH-LOGICAL-c419t-546f9b4f096021d54c2da620f02c5cfbf976b7477dc546628748bb1555d0d5853</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-015-3621-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-015-3621-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Karthik, A.</creatorcontrib><creatorcontrib>Arunmetha, S.</creatorcontrib><creatorcontrib>Srither, S. R.</creatorcontrib><creatorcontrib>Manivasakan, P.</creatorcontrib><creatorcontrib>Rajendran, V.</creatorcontrib><title>Nano alumina–zirconia blended epoxy polymeric composites for anticorrosive applications</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>Amorphous alumina–zirconia (Al
2
O
3
–ZrO
2
) nanoparticles were produced by hot-air spray pyrolysis method. Two and six layers of anticorrosive coating of epoxy polyamide (EP) resin and mixture of amorphous Al
2
O
3
–ZrO
2
nanoparticles in epoxy polyamide resin (NEP), respectively, were applied on SS 316L specimens. The performance of EP and NEP coated samples was comprehensively characterized. The results show that the sample with six layers of NEP coating (SSNEP6) has enhanced thermal, elastic properties and chemical resistance than that with six layers of EP coating (SSEP6). Thermo gravimetric analysis reveals that EP sample decomposed at 523 °C whereas NEP sample has extended thermal stability up to 750 °C with minimum residual mass. The thermal conductivity of EP sample is 0.124 while for NEP is about 0.263 W/mK. The hardness and reduced elastic modulus of SSNEP6 sample were, respectively, 318.32 MPa and 5.98 GPa whereas those of SSEP6 sample were 233.69 MPa and 4.17 GPa. Further, in-situ scanning probe microscopy (SPM)-nanoindentation and atomic force microscopy (AFM) images were obtained to explore the formation of Al
2
O
3
–ZrO
2
nano filler in EP matrix. The samples coated with multilayers of EP and NEP was exposed to acid immersion (10 % of H
2
SO
4
) for 48 h. The SPM and AFM microstructure images show that the NEP coated sample maintains its original surface feature with existing passive layer formation, whereas EP coated sample shows surface deterioration and deformation. In addition, stability of EP and NEP coated samples was measured in terms of surface roughness with respect to nano filler in epoxy matrix. This observation shows that Al
2
O
3
–ZrO
2
nanofiller can be used to improve the desirable properties in host epoxy matrix.</description><subject>Aluminum oxide</subject><subject>Atomic force microscopy</subject><subject>Austenitic stainless steels</subject><subject>Ceramics</subject><subject>Chemistry and Materials Science</subject><subject>Coating</subject><subject>Composites</subject><subject>Corrosion prevention</subject><subject>Corrosion resistance</subject><subject>Deformation</subject><subject>Elastic properties</subject><subject>Fillers</subject><subject>Formations</subject><subject>Glass</subject><subject>Gravimetric analysis</subject><subject>Heat resistant steels</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Microscopy</subject><subject>Modulus of elasticity</subject><subject>Multilayers</subject><subject>Nanoindentation</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>Optical and Electronic Materials</subject><subject>Organic chemistry</subject><subject>Original Paper</subject><subject>Polyamide resins</subject><subject>Protective coatings</subject><subject>Scanning probe microscopy</subject><subject>Spray pyrolysis</subject><subject>Submerging</subject><subject>Sulfuric acid</subject><subject>Surface roughness</subject><subject>Surface stability</subject><subject>Thermal conductivity</subject><subject>Thermal stability</subject><subject>Zirconium dioxide</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kMtKxDAUhoMoOF4ewF3BjZvqOWnStEsZvIHoRheuQpqmkqFNatIRx5Xv4Bv6JGYYQRBcHTh8_885HyFHCKcIIM4iQi0wB-R5UVLMqy0yQy6KnFWs3CYzqGmVgwCxS_ZiXAAAZyhm5OlOOZ-pfjlYp74-Pt9t0N5ZlTW9ca1pMzP6t1U2-n41mGB1pv0w-mgnE7POh0y5yWofQlq9mkyNY2-1mqx38YDsdKqP5vBn7pPHy4uH-XV-e391Mz-_zTXDeso5K7u6YR3UJVBsOdO0VSWFDqjmumu6WpSNYEK0OqElrQSrmgY55y20vOLFPjnZ9I7BvyxNnORgozZ9r5zxyyhRFElQhVQk9PgPuvDL4NJ1klJe8wIZrgtxQ-n0VQymk2OwgworiSDXsuVGtkyy5Vq2rFKGbjIxse7ZhN_m_0PfeUWDIw</recordid><startdate>20150501</startdate><enddate>20150501</enddate><creator>Karthik, A.</creator><creator>Arunmetha, S.</creator><creator>Srither, S. R.</creator><creator>Manivasakan, P.</creator><creator>Rajendran, V.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150501</creationdate><title>Nano alumina–zirconia blended epoxy polymeric composites for anticorrosive applications</title><author>Karthik, A. ; Arunmetha, S. ; Srither, S. R. ; Manivasakan, P. ; Rajendran, V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-546f9b4f096021d54c2da620f02c5cfbf976b7477dc546628748bb1555d0d5853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Aluminum oxide</topic><topic>Atomic force microscopy</topic><topic>Austenitic stainless steels</topic><topic>Ceramics</topic><topic>Chemistry and Materials Science</topic><topic>Coating</topic><topic>Composites</topic><topic>Corrosion prevention</topic><topic>Corrosion resistance</topic><topic>Deformation</topic><topic>Elastic properties</topic><topic>Fillers</topic><topic>Formations</topic><topic>Glass</topic><topic>Gravimetric analysis</topic><topic>Heat resistant steels</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Microscopy</topic><topic>Modulus of elasticity</topic><topic>Multilayers</topic><topic>Nanoindentation</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>Optical and Electronic Materials</topic><topic>Organic chemistry</topic><topic>Original Paper</topic><topic>Polyamide resins</topic><topic>Protective coatings</topic><topic>Scanning probe microscopy</topic><topic>Spray pyrolysis</topic><topic>Submerging</topic><topic>Sulfuric acid</topic><topic>Surface roughness</topic><topic>Surface stability</topic><topic>Thermal conductivity</topic><topic>Thermal stability</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karthik, A.</creatorcontrib><creatorcontrib>Arunmetha, S.</creatorcontrib><creatorcontrib>Srither, S. R.</creatorcontrib><creatorcontrib>Manivasakan, P.</creatorcontrib><creatorcontrib>Rajendran, V.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Aluminium Industry Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karthik, A.</au><au>Arunmetha, S.</au><au>Srither, S. R.</au><au>Manivasakan, P.</au><au>Rajendran, V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nano alumina–zirconia blended epoxy polymeric composites for anticorrosive applications</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2015-05-01</date><risdate>2015</risdate><volume>74</volume><issue>2</issue><spage>460</spage><epage>471</epage><pages>460-471</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>Amorphous alumina–zirconia (Al
2
O
3
–ZrO
2
) nanoparticles were produced by hot-air spray pyrolysis method. Two and six layers of anticorrosive coating of epoxy polyamide (EP) resin and mixture of amorphous Al
2
O
3
–ZrO
2
nanoparticles in epoxy polyamide resin (NEP), respectively, were applied on SS 316L specimens. The performance of EP and NEP coated samples was comprehensively characterized. The results show that the sample with six layers of NEP coating (SSNEP6) has enhanced thermal, elastic properties and chemical resistance than that with six layers of EP coating (SSEP6). Thermo gravimetric analysis reveals that EP sample decomposed at 523 °C whereas NEP sample has extended thermal stability up to 750 °C with minimum residual mass. The thermal conductivity of EP sample is 0.124 while for NEP is about 0.263 W/mK. The hardness and reduced elastic modulus of SSNEP6 sample were, respectively, 318.32 MPa and 5.98 GPa whereas those of SSEP6 sample were 233.69 MPa and 4.17 GPa. Further, in-situ scanning probe microscopy (SPM)-nanoindentation and atomic force microscopy (AFM) images were obtained to explore the formation of Al
2
O
3
–ZrO
2
nano filler in EP matrix. The samples coated with multilayers of EP and NEP was exposed to acid immersion (10 % of H
2
SO
4
) for 48 h. The SPM and AFM microstructure images show that the NEP coated sample maintains its original surface feature with existing passive layer formation, whereas EP coated sample shows surface deterioration and deformation. In addition, stability of EP and NEP coated samples was measured in terms of surface roughness with respect to nano filler in epoxy matrix. This observation shows that Al
2
O
3
–ZrO
2
nanofiller can be used to improve the desirable properties in host epoxy matrix.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10971-015-3621-8</doi><tpages>12</tpages></addata></record> |
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| identifier | ISSN: 0928-0707 |
| ispartof | Journal of sol-gel science and technology, 2015-05, Vol.74 (2), p.460-471 |
| issn | 0928-0707 1573-4846 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1730078127 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Aluminum oxide Atomic force microscopy Austenitic stainless steels Ceramics Chemistry and Materials Science Coating Composites Corrosion prevention Corrosion resistance Deformation Elastic properties Fillers Formations Glass Gravimetric analysis Heat resistant steels Inorganic Chemistry Materials Science Microscopy Modulus of elasticity Multilayers Nanoindentation Nanoparticles Nanostructure Nanotechnology Natural Materials Optical and Electronic Materials Organic chemistry Original Paper Polyamide resins Protective coatings Scanning probe microscopy Spray pyrolysis Submerging Sulfuric acid Surface roughness Surface stability Thermal conductivity Thermal stability Zirconium dioxide |
| title | Nano alumina–zirconia blended epoxy polymeric composites for anticorrosive applications |
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