Anion-dependent construction of two hexanuclear 3d-4f complexes with a flexible Schiff base ligand
Two hexanuclear 3d-4f Ni-Eu and Cu-Eu complexes [Eu(4)Ni(2)L(2)(OAc)(12)(EtOH)(2)] (1) and [Eu(4)Cu(2)L(2)(OAc)(12)]·2H(2)O (2) are reported which are formed from the salen type Schiff-base ligand H(2)L (H(2)L = N,N'-bis(3-methoxysalicylidene)butane-1,4-diamine). In both complexes, four Eu(3+)...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2012-01, Vol.41 (37), p.11449-11453 |
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| container_issue | 37 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Yang, Xiaoping Chan, Christopher Lam, Daniel Schipper, Desmond Stanley, Julie M Chen, Xiaoyan Jones, Richard A Holliday, Bradley J Wong, Wai-Kwok Chen, Shengchun Chen, Qun |
| description | Two hexanuclear 3d-4f Ni-Eu and Cu-Eu complexes [Eu(4)Ni(2)L(2)(OAc)(12)(EtOH)(2)] (1) and [Eu(4)Cu(2)L(2)(OAc)(12)]·2H(2)O (2) are reported which are formed from the salen type Schiff-base ligand H(2)L (H(2)L = N,N'-bis(3-methoxysalicylidene)butane-1,4-diamine). In both complexes, four Eu(3+) cations are bridged by eight OAc(-) groups and the chain is terminated at each end by two ML (M = Ni and Cu) units. The structures of 1 and 2 were determined by single crystal X-ray crystallographic studies and the luminescence properties of the free ligand and metal complexes in solution were measured. |
| doi_str_mv | 10.1039/c2dt31268a |
| format | Article |
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In both complexes, four Eu(3+) cations are bridged by eight OAc(-) groups and the chain is terminated at each end by two ML (M = Ni and Cu) units. The structures of 1 and 2 were determined by single crystal X-ray crystallographic studies and the luminescence properties of the free ligand and metal complexes in solution were measured.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c2dt31268a</identifier><identifier>PMID: 22892983</identifier><language>eng</language><publisher>England</publisher><subject>Anions ; Cations ; Chains ; Coordination Complexes - chemical synthesis ; Coordination Complexes - chemistry ; Copper ; Crystallography, X-Ray ; Ligands ; Luminescence ; Models, Molecular ; Molecular Structure ; Nickel ; Schiff bases ; Schiff Bases - chemistry ; X-rays</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2012-01, Vol.41 (37), p.11449-11453</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-9de2ce611e02bd566d2df6601a6d6beaba138d30ceec10077e05e68288af54723</citedby><cites>FETCH-LOGICAL-c389t-9de2ce611e02bd566d2df6601a6d6beaba138d30ceec10077e05e68288af54723</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22892983$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Xiaoping</creatorcontrib><creatorcontrib>Chan, Christopher</creatorcontrib><creatorcontrib>Lam, Daniel</creatorcontrib><creatorcontrib>Schipper, Desmond</creatorcontrib><creatorcontrib>Stanley, Julie M</creatorcontrib><creatorcontrib>Chen, Xiaoyan</creatorcontrib><creatorcontrib>Jones, Richard A</creatorcontrib><creatorcontrib>Holliday, Bradley J</creatorcontrib><creatorcontrib>Wong, Wai-Kwok</creatorcontrib><creatorcontrib>Chen, Shengchun</creatorcontrib><creatorcontrib>Chen, Qun</creatorcontrib><title>Anion-dependent construction of two hexanuclear 3d-4f complexes with a flexible Schiff base ligand</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Two hexanuclear 3d-4f Ni-Eu and Cu-Eu complexes [Eu(4)Ni(2)L(2)(OAc)(12)(EtOH)(2)] (1) and [Eu(4)Cu(2)L(2)(OAc)(12)]·2H(2)O (2) are reported which are formed from the salen type Schiff-base ligand H(2)L (H(2)L = N,N'-bis(3-methoxysalicylidene)butane-1,4-diamine). In both complexes, four Eu(3+) cations are bridged by eight OAc(-) groups and the chain is terminated at each end by two ML (M = Ni and Cu) units. The structures of 1 and 2 were determined by single crystal X-ray crystallographic studies and the luminescence properties of the free ligand and metal complexes in solution were measured.</description><subject>Anions</subject><subject>Cations</subject><subject>Chains</subject><subject>Coordination Complexes - chemical synthesis</subject><subject>Coordination Complexes - chemistry</subject><subject>Copper</subject><subject>Crystallography, X-Ray</subject><subject>Ligands</subject><subject>Luminescence</subject><subject>Models, Molecular</subject><subject>Molecular Structure</subject><subject>Nickel</subject><subject>Schiff bases</subject><subject>Schiff Bases - chemistry</subject><subject>X-rays</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqF0TtPwzAQB3ALgWgpLHwA5BEhBexz4thjVfGSKjEAc-TYZxqUF3Gilm9PUEsZO91Dv_svR8glZ7ecCX1nwfWCg1TmiEx5nKaRBhEf73uQE3IWwidjACyBUzIBUBq0ElOSz-uiqSOHLdYO657apg59N9h-XNPG037d0BVuTD3YEk1HhYtiP6qqLXGDga6LfkUN9eNU5CXSV7sqvKe5CUjL4sPU7pyceFMGvNjVGXl_uH9bPEXLl8fnxXwZWaF0H2mHYFFyjgxyl0jpwHkpGTfSyRxNbrhQTjCLaDljaYosQalAKeOTOAUxI9fb3LZrvgYMfVYVwWJZmhqbIWQ8FeOZYkwfpgBcSS7j9DBlQiU65kKO9GZLbdeE0KHP2q6oTPc9ol-ns_9PjfhqlzvkFbo9_XuN-AHsS443</recordid><startdate>20120101</startdate><enddate>20120101</enddate><creator>Yang, Xiaoping</creator><creator>Chan, Christopher</creator><creator>Lam, Daniel</creator><creator>Schipper, Desmond</creator><creator>Stanley, Julie M</creator><creator>Chen, Xiaoyan</creator><creator>Jones, Richard A</creator><creator>Holliday, Bradley J</creator><creator>Wong, Wai-Kwok</creator><creator>Chen, Shengchun</creator><creator>Chen, Qun</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>7SR</scope><scope>8BQ</scope><scope>JG9</scope></search><sort><creationdate>20120101</creationdate><title>Anion-dependent construction of two hexanuclear 3d-4f complexes with a flexible Schiff base ligand</title><author>Yang, Xiaoping ; Chan, Christopher ; Lam, Daniel ; Schipper, Desmond ; Stanley, Julie M ; Chen, Xiaoyan ; Jones, Richard A ; Holliday, Bradley J ; Wong, Wai-Kwok ; Chen, Shengchun ; Chen, Qun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-9de2ce611e02bd566d2df6601a6d6beaba138d30ceec10077e05e68288af54723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Anions</topic><topic>Cations</topic><topic>Chains</topic><topic>Coordination Complexes - chemical synthesis</topic><topic>Coordination Complexes - chemistry</topic><topic>Copper</topic><topic>Crystallography, X-Ray</topic><topic>Ligands</topic><topic>Luminescence</topic><topic>Models, Molecular</topic><topic>Molecular Structure</topic><topic>Nickel</topic><topic>Schiff bases</topic><topic>Schiff Bases - chemistry</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Xiaoping</creatorcontrib><creatorcontrib>Chan, Christopher</creatorcontrib><creatorcontrib>Lam, Daniel</creatorcontrib><creatorcontrib>Schipper, Desmond</creatorcontrib><creatorcontrib>Stanley, Julie M</creatorcontrib><creatorcontrib>Chen, Xiaoyan</creatorcontrib><creatorcontrib>Jones, Richard A</creatorcontrib><creatorcontrib>Holliday, Bradley J</creatorcontrib><creatorcontrib>Wong, Wai-Kwok</creatorcontrib><creatorcontrib>Chen, Shengchun</creatorcontrib><creatorcontrib>Chen, Qun</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Materials Research Database</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Xiaoping</au><au>Chan, Christopher</au><au>Lam, Daniel</au><au>Schipper, Desmond</au><au>Stanley, Julie M</au><au>Chen, Xiaoyan</au><au>Jones, Richard A</au><au>Holliday, Bradley J</au><au>Wong, Wai-Kwok</au><au>Chen, Shengchun</au><au>Chen, Qun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anion-dependent construction of two hexanuclear 3d-4f complexes with a flexible Schiff base ligand</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2012-01-01</date><risdate>2012</risdate><volume>41</volume><issue>37</issue><spage>11449</spage><epage>11453</epage><pages>11449-11453</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Two hexanuclear 3d-4f Ni-Eu and Cu-Eu complexes [Eu(4)Ni(2)L(2)(OAc)(12)(EtOH)(2)] (1) and [Eu(4)Cu(2)L(2)(OAc)(12)]·2H(2)O (2) are reported which are formed from the salen type Schiff-base ligand H(2)L (H(2)L = N,N'-bis(3-methoxysalicylidene)butane-1,4-diamine). In both complexes, four Eu(3+) cations are bridged by eight OAc(-) groups and the chain is terminated at each end by two ML (M = Ni and Cu) units. The structures of 1 and 2 were determined by single crystal X-ray crystallographic studies and the luminescence properties of the free ligand and metal complexes in solution were measured.</abstract><cop>England</cop><pmid>22892983</pmid><doi>10.1039/c2dt31268a</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anions Cations Chains Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Copper Crystallography, X-Ray Ligands Luminescence Models, Molecular Molecular Structure Nickel Schiff bases Schiff Bases - chemistry X-rays |
| title | Anion-dependent construction of two hexanuclear 3d-4f complexes with a flexible Schiff base ligand |
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