Metal (Mg, Fe, Co, Zr and Ti) complexes derived from aminosilyl substituted aminopyridinato ligand: synthesis, structures and ethylene polymerization behaviors of the group 4 complexes

Lithium N-[(N,N-dimethylamino)dimethylsilyl]-2-pyridylamidate (2) was prepared from the reaction of new compound N-[(N,N-dimethylamino)dimethylsilyl]-2-pyridylamine (1) and LiBu(n). Treatment of the lithium salt (2) with an equal equivalent of MgBr(2)(THF)(2), FeCl(2) and CoCl(2) afforded the corres...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2012-08, Vol.41 (31), p.9460-9467
Hauptverfasser:	Duan, Xin-E, Yuan, Shi-Fang, Tong, Hong-Bo, Bai, Sheng-Di, Wei, Xue-Hong, Liu, Dian-Sheng
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Equivalence Ethylene Ligands Lithium Polymerization Titanium Zirconium
Online-Zugang:	Volltext
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