Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates

The regioselective addition of α-aminoalkyl radicals to 2,3-allenoates by visible-light-mediated electron transfer using 1 mol% of Ru(bpy) 3 (BF 4 ) 2 as a photocatalyst was successfully established. This photoredox protocol is a simple and effective method for the synthesis of unsaturated γ-aminobu...

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Veröffentlicht in:	RSC advances 2015-01, Vol.5 (68), p.55290-55294
Hauptverfasser:	Dai, Xiaojun, Mao, Renjie, Guan, Baochuan, Xu, Xiaoliang, Li, Xiaonian
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Derivatives Electron transfer Esters Photocatalysis Radicals Synthesis Unsaturated
Online-Zugang:	Volltext
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