Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates
The regioselective addition of α-aminoalkyl radicals to 2,3-allenoates by visible-light-mediated electron transfer using 1 mol% of Ru(bpy) 3 (BF 4 ) 2 as a photocatalyst was successfully established. This photoredox protocol is a simple and effective method for the synthesis of unsaturated γ-aminobu...
Gespeichert in:
| Veröffentlicht in: | RSC advances 2015-01, Vol.5 (68), p.55290-55294 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 55294 |
|---|---|
| container_issue | 68 |
| container_start_page | 55290 |
| container_title | RSC advances |
| container_volume | 5 |
| creator | Dai, Xiaojun Mao, Renjie Guan, Baochuan Xu, Xiaoliang Li, Xiaonian |
| description | The regioselective addition of α-aminoalkyl radicals to 2,3-allenoates by visible-light-mediated electron transfer using 1 mol% of Ru(bpy)
3
(BF
4
)
2
as a photocatalyst was successfully established. This photoredox protocol is a simple and effective method for the synthesis of unsaturated γ-aminobutyric ester derivatives. |
| doi_str_mv | 10.1039/C5RA10491B |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1730073916</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1730073916</sourcerecordid><originalsourceid>FETCH-LOGICAL-c330t-384b0f059d49960976f0ad5ca02a8d1e9eaef60351783e816c4c37f68960c6e13</originalsourceid><addsrcrecordid>eNpNkE1LAzEURYMoWGo3_oIsRRx9mcxkJu5q8QsKgqjbIU1e2mja1CQV--8dqaJ38y6cw1tcQo4ZnDPg8mJSP44ZVJJd7ZFBCZUoShBy_18_JKOUXqGPqFkp2ID4F5fczCP1br7IdL0IOUQ04ZNqlZXfJpcuacS5Cwk96uw-kEZlnFaeKmNcdmFFg6Vq6VZB-bet_8WJ5kDLM14o77FnGdMRObA9wNHPHZLnm-unyV0xfbi9n4ynheYccsHbagYWamkqKQXIRlhQptYKStUahhIVWgG8Zk3LsWVCV5o3VrS9rAUyPiQnu7_rGN43mHK3dEmj92qFYZM61nCAhksmevV0p-oYUopou3V0SxW3HYPue9Xub1X-BbIaaks</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1730073916</pqid></control><display><type>article</type><title>Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Dai, Xiaojun ; Mao, Renjie ; Guan, Baochuan ; Xu, Xiaoliang ; Li, Xiaonian</creator><creatorcontrib>Dai, Xiaojun ; Mao, Renjie ; Guan, Baochuan ; Xu, Xiaoliang ; Li, Xiaonian</creatorcontrib><description>The regioselective addition of α-aminoalkyl radicals to 2,3-allenoates by visible-light-mediated electron transfer using 1 mol% of Ru(bpy)
3
(BF
4
)
2
as a photocatalyst was successfully established. This photoredox protocol is a simple and effective method for the synthesis of unsaturated γ-aminobutyric ester derivatives.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C5RA10491B</identifier><language>eng</language><subject>Catalysis ; Derivatives ; Electron transfer ; Esters ; Photocatalysis ; Radicals ; Synthesis ; Unsaturated</subject><ispartof>RSC advances, 2015-01, Vol.5 (68), p.55290-55294</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c330t-384b0f059d49960976f0ad5ca02a8d1e9eaef60351783e816c4c37f68960c6e13</citedby><cites>FETCH-LOGICAL-c330t-384b0f059d49960976f0ad5ca02a8d1e9eaef60351783e816c4c37f68960c6e13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Dai, Xiaojun</creatorcontrib><creatorcontrib>Mao, Renjie</creatorcontrib><creatorcontrib>Guan, Baochuan</creatorcontrib><creatorcontrib>Xu, Xiaoliang</creatorcontrib><creatorcontrib>Li, Xiaonian</creatorcontrib><title>Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates</title><title>RSC advances</title><description>The regioselective addition of α-aminoalkyl radicals to 2,3-allenoates by visible-light-mediated electron transfer using 1 mol% of Ru(bpy)
3
(BF
4
)
2
as a photocatalyst was successfully established. This photoredox protocol is a simple and effective method for the synthesis of unsaturated γ-aminobutyric ester derivatives.</description><subject>Catalysis</subject><subject>Derivatives</subject><subject>Electron transfer</subject><subject>Esters</subject><subject>Photocatalysis</subject><subject>Radicals</subject><subject>Synthesis</subject><subject>Unsaturated</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpNkE1LAzEURYMoWGo3_oIsRRx9mcxkJu5q8QsKgqjbIU1e2mja1CQV--8dqaJ38y6cw1tcQo4ZnDPg8mJSP44ZVJJd7ZFBCZUoShBy_18_JKOUXqGPqFkp2ID4F5fczCP1br7IdL0IOUQ04ZNqlZXfJpcuacS5Cwk96uw-kEZlnFaeKmNcdmFFg6Vq6VZB-bet_8WJ5kDLM14o77FnGdMRObA9wNHPHZLnm-unyV0xfbi9n4ynheYccsHbagYWamkqKQXIRlhQptYKStUahhIVWgG8Zk3LsWVCV5o3VrS9rAUyPiQnu7_rGN43mHK3dEmj92qFYZM61nCAhksmevV0p-oYUopou3V0SxW3HYPue9Xub1X-BbIaaks</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Dai, Xiaojun</creator><creator>Mao, Renjie</creator><creator>Guan, Baochuan</creator><creator>Xu, Xiaoliang</creator><creator>Li, Xiaonian</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20150101</creationdate><title>Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates</title><author>Dai, Xiaojun ; Mao, Renjie ; Guan, Baochuan ; Xu, Xiaoliang ; Li, Xiaonian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c330t-384b0f059d49960976f0ad5ca02a8d1e9eaef60351783e816c4c37f68960c6e13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Catalysis</topic><topic>Derivatives</topic><topic>Electron transfer</topic><topic>Esters</topic><topic>Photocatalysis</topic><topic>Radicals</topic><topic>Synthesis</topic><topic>Unsaturated</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dai, Xiaojun</creatorcontrib><creatorcontrib>Mao, Renjie</creatorcontrib><creatorcontrib>Guan, Baochuan</creatorcontrib><creatorcontrib>Xu, Xiaoliang</creatorcontrib><creatorcontrib>Li, Xiaonian</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dai, Xiaojun</au><au>Mao, Renjie</au><au>Guan, Baochuan</au><au>Xu, Xiaoliang</au><au>Li, Xiaonian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates</atitle><jtitle>RSC advances</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>5</volume><issue>68</issue><spage>55290</spage><epage>55294</epage><pages>55290-55294</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>The regioselective addition of α-aminoalkyl radicals to 2,3-allenoates by visible-light-mediated electron transfer using 1 mol% of Ru(bpy)
3
(BF
4
)
2
as a photocatalyst was successfully established. This photoredox protocol is a simple and effective method for the synthesis of unsaturated γ-aminobutyric ester derivatives.</abstract><doi>10.1039/C5RA10491B</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2015-01, Vol.5 (68), p.55290-55294 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1730073916 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Catalysis Derivatives Electron transfer Esters Photocatalysis Radicals Synthesis Unsaturated |
| title | Visible light photoredox catalysis: regioselective radical addition of aminoalkyl radicals to 2,3-allenoates |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-21T18%3A00%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Visible%20light%20photoredox%20catalysis:%20regioselective%20radical%20addition%20of%20aminoalkyl%20radicals%20to%202,3-allenoates&rft.jtitle=RSC%20advances&rft.au=Dai,%20Xiaojun&rft.date=2015-01-01&rft.volume=5&rft.issue=68&rft.spage=55290&rft.epage=55294&rft.pages=55290-55294&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/C5RA10491B&rft_dat=%3Cproquest_cross%3E1730073916%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1730073916&rft_id=info:pmid/&rfr_iscdi=true |