Triple-stranded ferric helices: a pi - pi interaction-driven structural hierarchy of Fe sub(5), Fe sub(7), and Fe sub(17) clusters

Three polypyridine ligand-supported multinuclear iron complexes, [Fe sub(5)], [Fe sub(7)] and [Fe sub(17)], were synthesized and their physical properties were investigated. The complexes had triple-stranded helical structures with pseudo threefold symmetry, and were stabilized by varying degrees of...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2013-10, Vol.42 (45), p.16185-16193
Hauptverfasser:	Shiga, Takuya, Noguchi, Mao, Sato, Hiroki, Matsumoto, Takuto, Newton, Graham N, Oshio, Hiroki
Format:	Artikel
Sprache:	eng
Schlagworte:	Clusters Helical Iron Ligands Neighbouring Physical properties Stacking Symmetry
Online-Zugang:	Volltext
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