Magnesium complexes supported by salan-like ligands: synthesis, characterization and their application in the ring-opening polymerization of rac-lactide

A series of magnesium silylamido complexes bearing salan-like multidentate aminophenolate ligands, [(L(1–4))MgN(SiMe3)2] (1–4) and [(L1)MgN(SiHMe2)2] (1′) (L(1–4) = –OAr1N(Me)(CH2)nN(Me)Ar2, n = 2 or 3), have been synthesized via the reaction of Mg[N(SiMe3)2]2 or Mg[N(SiHMe2)2] with 1 equiv. of the...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2013-10, Vol.42 (39), p.14200-14211
Hauptverfasser:	Song, Shaodi, Ma, Haiyan, Yang, Yang
Format:	Artikel
Sprache:	eng
Schlagworte:	Aminophenol Catalytic activity Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Crystallography, X-Ray Dioxanes - chemistry Electronics Isotactic Ligands Magnesium Magnesium - chemistry Magnetic Resonance Spectroscopy Molecular Conformation Polymerization Stereoselectivity
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