Single and double crown macrocyclic derivatives of cyclotriphosphazene as receptors of silver( i ) ions
We report the preparation of new single and double PNP-lariat ether derivatives. L1 was synthesized from a MONO-ANSA precursor and L2 was synthesized from a BIS-ANSA precursor by subsequent substitution of the chlorine atoms. The reactive chlorine atoms were substituted by piperidinyl groups. Their...
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| Veröffentlicht in: | RSC advances 2015-01, Vol.5 (48), p.38435-38442 |
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| container_issue | 48 |
| container_start_page | 38435 |
| container_title | RSC advances |
| container_volume | 5 |
| creator | Gutowska, Natalia Seliger, Piotr Andrijewski, Grzegorz Siwy, Mariola Małecka, Magdalena Kusz, Joachim |
| description | We report the preparation of new single and double PNP-lariat ether derivatives.
L1
was synthesized from a MONO-ANSA precursor and
L2
was synthesized from a BIS-ANSA precursor by subsequent substitution of the chlorine atoms. The reactive chlorine atoms were substituted by piperidinyl groups. Their structures were established by elemental analysis, MS,
1
H NMR,
31
P NMR and
13
C NMR spectroscopy. Furthermore, this work includes an investigation of the complexation of silver(
i
) ions by the two new ligands in methanol and acetonitrile solutions.
1
H NMR,
31
P NMR and
13
C NMR spectra were recorded to investigate how the complexation of silver(
i
) ions by the investigated macrocyclic ligands occurs. |
| doi_str_mv | 10.1039/C5RA02469B |
| format | Article |
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L1
was synthesized from a MONO-ANSA precursor and
L2
was synthesized from a BIS-ANSA precursor by subsequent substitution of the chlorine atoms. The reactive chlorine atoms were substituted by piperidinyl groups. Their structures were established by elemental analysis, MS,
1
H NMR,
31
P NMR and
13
C NMR spectroscopy. Furthermore, this work includes an investigation of the complexation of silver(
i
) ions by the two new ligands in methanol and acetonitrile solutions.
1
H NMR,
31
P NMR and
13
C NMR spectra were recorded to investigate how the complexation of silver(
i
) ions by the investigated macrocyclic ligands occurs.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C5RA02469B</identifier><language>eng</language><subject>Chlorine ; Complexation ; Derivatives ; Ligands ; Macrocyclic compounds ; Methyl alcohol ; Nuclear magnetic resonance ; Precursors ; Spectra</subject><ispartof>RSC advances, 2015-01, Vol.5 (48), p.38435-38442</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c264t-7220a9631ad286036367aedac039c55ecdf82edb4e071bb269985239ff488823</citedby><cites>FETCH-LOGICAL-c264t-7220a9631ad286036367aedac039c55ecdf82edb4e071bb269985239ff488823</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Gutowska, Natalia</creatorcontrib><creatorcontrib>Seliger, Piotr</creatorcontrib><creatorcontrib>Andrijewski, Grzegorz</creatorcontrib><creatorcontrib>Siwy, Mariola</creatorcontrib><creatorcontrib>Małecka, Magdalena</creatorcontrib><creatorcontrib>Kusz, Joachim</creatorcontrib><title>Single and double crown macrocyclic derivatives of cyclotriphosphazene as receptors of silver( i ) ions</title><title>RSC advances</title><description>We report the preparation of new single and double PNP-lariat ether derivatives.
L1
was synthesized from a MONO-ANSA precursor and
L2
was synthesized from a BIS-ANSA precursor by subsequent substitution of the chlorine atoms. The reactive chlorine atoms were substituted by piperidinyl groups. Their structures were established by elemental analysis, MS,
1
H NMR,
31
P NMR and
13
C NMR spectroscopy. Furthermore, this work includes an investigation of the complexation of silver(
i
) ions by the two new ligands in methanol and acetonitrile solutions.
1
H NMR,
31
P NMR and
13
C NMR spectra were recorded to investigate how the complexation of silver(
i
) ions by the investigated macrocyclic ligands occurs.</description><subject>Chlorine</subject><subject>Complexation</subject><subject>Derivatives</subject><subject>Ligands</subject><subject>Macrocyclic compounds</subject><subject>Methyl alcohol</subject><subject>Nuclear magnetic resonance</subject><subject>Precursors</subject><subject>Spectra</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpNkF9LwzAUxYMoOOZe_AR5nEL1JmnT5nEO_8FA0L2XNLndIl1Tk24yP72dE_S-nMPldy-cQ8glgxsGQt3Os9cZ8FSquxMy4pDKhINUp__8OZnE-A7DyIxxyUZk9ebaVYNUt5Zav60Ga4L_bOlGD2r2pnGGWgxup3u3w0h9TQ9b3wfXrX3s1voL2-E-0oAGu96HHya6ZodhSh29os638YKc1bqJOPnVMVk-3C_nT8ni5fF5Plskhsu0T3LOQSspmLa8kCCkkLlGq82Qz2QZGlsXHG2VIuSsqrhUqsi4UHWdFkXBxZhMj2-74D-2GPty46LBptEt-m0sWS4AclCgBvT6iA45YwxYl11wGx32JYPy0Gf516f4BrsUaA4</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Gutowska, Natalia</creator><creator>Seliger, Piotr</creator><creator>Andrijewski, Grzegorz</creator><creator>Siwy, Mariola</creator><creator>Małecka, Magdalena</creator><creator>Kusz, Joachim</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20150101</creationdate><title>Single and double crown macrocyclic derivatives of cyclotriphosphazene as receptors of silver( i ) ions</title><author>Gutowska, Natalia ; Seliger, Piotr ; Andrijewski, Grzegorz ; Siwy, Mariola ; Małecka, Magdalena ; Kusz, Joachim</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c264t-7220a9631ad286036367aedac039c55ecdf82edb4e071bb269985239ff488823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chlorine</topic><topic>Complexation</topic><topic>Derivatives</topic><topic>Ligands</topic><topic>Macrocyclic compounds</topic><topic>Methyl alcohol</topic><topic>Nuclear magnetic resonance</topic><topic>Precursors</topic><topic>Spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gutowska, Natalia</creatorcontrib><creatorcontrib>Seliger, Piotr</creatorcontrib><creatorcontrib>Andrijewski, Grzegorz</creatorcontrib><creatorcontrib>Siwy, Mariola</creatorcontrib><creatorcontrib>Małecka, Magdalena</creatorcontrib><creatorcontrib>Kusz, Joachim</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gutowska, Natalia</au><au>Seliger, Piotr</au><au>Andrijewski, Grzegorz</au><au>Siwy, Mariola</au><au>Małecka, Magdalena</au><au>Kusz, Joachim</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Single and double crown macrocyclic derivatives of cyclotriphosphazene as receptors of silver( i ) ions</atitle><jtitle>RSC advances</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>5</volume><issue>48</issue><spage>38435</spage><epage>38442</epage><pages>38435-38442</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>We report the preparation of new single and double PNP-lariat ether derivatives.
L1
was synthesized from a MONO-ANSA precursor and
L2
was synthesized from a BIS-ANSA precursor by subsequent substitution of the chlorine atoms. The reactive chlorine atoms were substituted by piperidinyl groups. Their structures were established by elemental analysis, MS,
1
H NMR,
31
P NMR and
13
C NMR spectroscopy. Furthermore, this work includes an investigation of the complexation of silver(
i
) ions by the two new ligands in methanol and acetonitrile solutions.
1
H NMR,
31
P NMR and
13
C NMR spectra were recorded to investigate how the complexation of silver(
i
) ions by the investigated macrocyclic ligands occurs.</abstract><doi>10.1039/C5RA02469B</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2015-01, Vol.5 (48), p.38435-38442 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1730070909 |
| source | Royal Society Of Chemistry Journals |
| subjects | Chlorine Complexation Derivatives Ligands Macrocyclic compounds Methyl alcohol Nuclear magnetic resonance Precursors Spectra |
| title | Single and double crown macrocyclic derivatives of cyclotriphosphazene as receptors of silver( i ) ions |
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