Redox and complexation chemistry of the Cr super(VI)/Cr super(V)-[sma ll caps]d-glucaric acid system

When an excess of uronic acid over Cr super(VI) is used, the oxidation of d-glucaric acid (Glucar) by Cr super(VI) yields d-arabinaric acid, CO sub(2) and Cr super(III)-Glucar complex as final redox products. The redox reaction involves the formation of intermediate Cr super(IV) and Cr super(V) spec...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-05, Vol.43 (24), p.9242-9254
Hauptverfasser:	Mangiameli, Maria Florencia, Gonzalez, Juan Carlos, Bellu, Sebastian, Bertoni, Fernando, Sala, Luis F
Format:	Artikel
Sprache:	eng
Schlagworte:	Complexation Electron paramagnetic resonance Free radicals In vitro testing Instability Redox reactions Surgical implants
Online-Zugang:	Volltext
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