A new PC(sp(3))P ligand and its coordination chemistry with low-valent iron, cobalt and nickel complexes
A new PC(sp(3))P ligand N,N'-bis(diphenylphosphino)dipyrromethane [PCH2P] (1) was prepared and its iron, cobalt and nickel chemistry was explored. Two pincer-type complexes [PCHP]Fe(H)(PMe3)2 (2) and [PCHP]Co(PMe3)2 (4) were synthesized in the reaction of with Fe(PMe3)4 and Co(Me)(PMe3)4. 1 rea...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2014-06, Vol.43 (23), p.8595-8598 |
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| container_issue | 23 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Zhu, Gengyu Li, Xiaoyan Xu, Guoqiang Wang, Lin Sun, Hongjian |
| description | A new PC(sp(3))P ligand N,N'-bis(diphenylphosphino)dipyrromethane [PCH2P] (1) was prepared and its iron, cobalt and nickel chemistry was explored. Two pincer-type complexes [PCHP]Fe(H)(PMe3)2 (2) and [PCHP]Co(PMe3)2 (4) were synthesized in the reaction of with Fe(PMe3)4 and Co(Me)(PMe3)4. 1 reacted with Co(PMe3)4 and Ni(PMe3)4 to afford Co(0) and Ni(0) complexes [PCH2P]Co(PMe3)2 (3) and [PCH2P]Ni(PMe3)2 (5). The structures of complexes 2-5 were determined by X-ray diffraction. |
| doi_str_mv | 10.1039/c4dt00639a |
| format | Article |
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Two pincer-type complexes [PCHP]Fe(H)(PMe3)2 (2) and [PCHP]Co(PMe3)2 (4) were synthesized in the reaction of with Fe(PMe3)4 and Co(Me)(PMe3)4. 1 reacted with Co(PMe3)4 and Ni(PMe3)4 to afford Co(0) and Ni(0) complexes [PCH2P]Co(PMe3)2 (3) and [PCH2P]Ni(PMe3)2 (5). 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The structures of complexes 2-5 were determined by X-ray diffraction.</description><subject>Cobalt</subject><subject>Cobalt - chemistry</subject><subject>Coordination Complexes - chemical synthesis</subject><subject>Coordination Complexes - chemistry</subject><subject>Diffraction</subject><subject>Iron</subject><subject>Iron - chemistry</subject><subject>Ligands</subject><subject>Molecular Structure</subject><subject>Nickel</subject><subject>Nickel - chemistry</subject><subject>Phosphines - chemistry</subject><subject>Pyrroles - chemistry</subject><subject>X-rays</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkctOwzAQRS0EoqWw4QOQly0i4PiVzrIKTwmJLso6chyHGtykxC6lf0_6oFtYjO5odOZqNBeh85hcx4TBjeZFIEQyUAeoG_MkiYAyfrjvqeygE-_fCaGUCHqMOpQnQAF4F01HuDJLPE77ft5ng8EYO_umqgKvywaPdV03ha1UsHWF9dTMrA_NCi9tmGJXL6Mv5UwVsG3q6qqFc-XCZrey-sO4djKbO_Nt_Ck6KpXz5mynPfR6fzdJH6Pnl4endPQcaSZYiDiNCae6FDSXdKg1TwwIWgopc2qYGkoNCZRFoTRhFHIGOShmTKwKoK1w1kP9re-8qT8XxoesvVgb51Rl6oXP4oS1vyIiGf6NCgFSDjn8w1VQmTAGHFr0covqpva-MWU2b-xMNassJtk6ryzlt5NNXqMWvtj5LvKZKfbob0DsB5Fnjtc</recordid><startdate>20140621</startdate><enddate>20140621</enddate><creator>Zhu, Gengyu</creator><creator>Li, Xiaoyan</creator><creator>Xu, Guoqiang</creator><creator>Wang, Lin</creator><creator>Sun, Hongjian</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>7SR</scope><scope>8BQ</scope><scope>JG9</scope></search><sort><creationdate>20140621</creationdate><title>A new PC(sp(3))P ligand and its coordination chemistry with low-valent iron, cobalt and nickel complexes</title><author>Zhu, Gengyu ; Li, Xiaoyan ; Xu, Guoqiang ; Wang, Lin ; Sun, Hongjian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-421042cf52b628cc47e952f566b2e3a86c979fddac0329b39b9a3ee1ad92ee143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Cobalt</topic><topic>Cobalt - chemistry</topic><topic>Coordination Complexes - chemical synthesis</topic><topic>Coordination Complexes - chemistry</topic><topic>Diffraction</topic><topic>Iron</topic><topic>Iron - chemistry</topic><topic>Ligands</topic><topic>Molecular Structure</topic><topic>Nickel</topic><topic>Nickel - chemistry</topic><topic>Phosphines - chemistry</topic><topic>Pyrroles - chemistry</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhu, Gengyu</creatorcontrib><creatorcontrib>Li, Xiaoyan</creatorcontrib><creatorcontrib>Xu, Guoqiang</creatorcontrib><creatorcontrib>Wang, Lin</creatorcontrib><creatorcontrib>Sun, Hongjian</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Materials Research Database</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhu, Gengyu</au><au>Li, Xiaoyan</au><au>Xu, Guoqiang</au><au>Wang, Lin</au><au>Sun, Hongjian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new PC(sp(3))P ligand and its coordination chemistry with low-valent iron, cobalt and nickel complexes</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2014-06-21</date><risdate>2014</risdate><volume>43</volume><issue>23</issue><spage>8595</spage><epage>8598</epage><pages>8595-8598</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A new PC(sp(3))P ligand N,N'-bis(diphenylphosphino)dipyrromethane [PCH2P] (1) was prepared and its iron, cobalt and nickel chemistry was explored. 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| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2014-06, Vol.43 (23), p.8595-8598 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Cobalt Cobalt - chemistry Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Diffraction Iron Iron - chemistry Ligands Molecular Structure Nickel Nickel - chemistry Phosphines - chemistry Pyrroles - chemistry X-rays |
| title | A new PC(sp(3))P ligand and its coordination chemistry with low-valent iron, cobalt and nickel complexes |
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