CARS at a "hard-to-realize conditions": lineshape spectroscopy at high temperatures in a real flame

On the example of the study of the collisional broadening and shift of the hydrogen Q-branch lines due to collisions with water molecules in wide temperatures range [2000 K -3000 K], we display the use of single-short CARS-spectroscopy for lineshape analisys at experimental conditions in which the o...

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Veröffentlicht in:Journal of physics. Conference series 2012-01, Vol.397 (1), p.12057-8
Hauptverfasser: Vereschagin, K A, Vereschagin, A K, Smirnov, V V, Stel'makh, O M, Fabelinsky, V I, Clauss, W, Oschwald, M
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container_end_page 8
container_issue 1
container_start_page 12057
container_title Journal of physics. Conference series
container_volume 397
creator Vereschagin, K A
Vereschagin, A K
Smirnov, V V
Stel'makh, O M
Fabelinsky, V I
Clauss, W
Oschwald, M
description On the example of the study of the collisional broadening and shift of the hydrogen Q-branch lines due to collisions with water molecules in wide temperatures range [2000 K -3000 K], we display the use of single-short CARS-spectroscopy for lineshape analisys at experimental conditions in which the object naturally does not exist, but can be created due to some physical and/or chemical processes for some time, small in comparison with the time necessary for stationary laboratory researches. Importance of light statistics as well as some specific features of CARS spectroscopy, which are the most actual from the point of view of use of CARS as a tool for lineshape spectroscopy, are discussed.
doi_str_mv 10.1088/1742-6596/397/1/012057
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subjects Chemical reactions
Collisional broadening
Collisions
High temperature
Physics
Raman scattering
Spectroscopy
Spectrum analysis
Statistics
Water chemistry
title CARS at a "hard-to-realize conditions": lineshape spectroscopy at high temperatures in a real flame
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