Ammine Calcium and Strontium Borohydrides: Syntheses, Structures, and Properties

A new series of solvent‐ and halide‐free ammine strontium metal borohydrides Sr(NH3)n(BH4)2 (n=1, 2, and 4) and further investigations of Ca(NH3)n(BH4)2 (n=1, 2, 4, and 6) are presented. Crystal structures have been determined by powder XRD and optimized by DFT calculations to evaluate the strength...

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Veröffentlicht in:	ChemSusChem 2015-10, Vol.8 (20), p.3472-3482
Hauptverfasser:	Jepsen, Lars H., Lee, Young-Su, Černý, Radovan, Sarusie, Ram S., Cho, Young Whan, Besenbacher, Flemming, Jensen, Torben R.
Format:	Artikel
Sprache:	eng
Schlagworte:	alkaline earth metals Ammonia - chemistry Borohydrides - chemical synthesis Borohydrides - chemistry boron Calcium Calcium - chemistry hydrogen Molecular Structure Powder Diffraction reaction mechanisms Spectroscopy, Fourier Transform Infrared Strontium - chemistry structure elucidation X-Ray Diffraction
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