Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides
The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2015-08, Vol.51 (64), p.12724-12727 |
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| container_end_page | 12727 |
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| container_issue | 64 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 51 |
| creator | Karanjit, Sangita Jinasan, Atchaleeya Samsook, Ekasith Dhital, Raghu N Motomiya, Kenichi Sato, Yoshinori Tohji, Kazuyuki Sakurai, Hidehiro |
| description | The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction by in situ generated Au-rich bimetallic Au/Pd nanoclusters. |
| doi_str_mv | 10.1039/c5cc04432d |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2015-08, Vol.51 (64), p.12724-12727 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1718963047 |
| source | MEDLINE; Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Aromatic compounds Bimetals Catalysis Chlorides Chlorides - chemistry Dechlorination Gold - chemistry Halogenation Hydrodechlorination Metal Nanoparticles - chemistry Models, Molecular Molecular Conformation Nanostructure Palladium Palladium - chemistry Stabilization |
| title | Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides |
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