Multicomponent reassembly of terpyridine-based materials: quantitative metallomacrocyclic rearrangement

Mixing of metallocyclic trimers and tetramers in an exact 1 : 1.5 stoichiometry provided new supramolecular triangles in quantitative yields. Characterization of the new hetero-nuclear metallomacrocycles was achieved by (1)H, 2D-COSY, 2D-NOESY, and (13)C NMR spectroscopy, along with ESI and TWIM mas...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-08, Vol.51 (64), p.12851-12854
Hauptverfasser:	Sarkar, Rajarshi, Guo, Zaihong, Li, Jingyi, Burai, Tarak N, Moorefield, Charles, Wesdemiotis, Chrys, Newkome, George R
Format:	Artikel
Sprache:	eng
Schlagworte:	Macrocyclic Compounds - chemistry Mass spectrometry Models, Molecular Molecular Conformation NMR spectroscopy Organometallic Compounds - chemistry Polymerization Pyridines - chemistry Stability Stoichiometry Triangles Trimers
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