Multicomponent reassembly of terpyridine-based materials: quantitative metallomacrocyclic rearrangement
Mixing of metallocyclic trimers and tetramers in an exact 1 : 1.5 stoichiometry provided new supramolecular triangles in quantitative yields. Characterization of the new hetero-nuclear metallomacrocycles was achieved by (1)H, 2D-COSY, 2D-NOESY, and (13)C NMR spectroscopy, along with ESI and TWIM mas...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2015-08, Vol.51 (64), p.12851-12854 |
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| container_end_page | 12854 |
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| container_issue | 64 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 51 |
| creator | Sarkar, Rajarshi Guo, Zaihong Li, Jingyi Burai, Tarak N Moorefield, Charles Wesdemiotis, Chrys Newkome, George R |
| description | Mixing of metallocyclic trimers and tetramers in an exact 1 : 1.5 stoichiometry provided new supramolecular triangles in quantitative yields. Characterization of the new hetero-nuclear metallomacrocycles was achieved by (1)H, 2D-COSY, 2D-NOESY, and (13)C NMR spectroscopy, along with ESI and TWIM mass spectrometry. Gradient tandem MS (gMS(2)) provided insight into the stabilities of the binuclear structures. |
| doi_str_mv | 10.1039/c5cc05048k |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2015-08, Vol.51 (64), p.12851-12854 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Macrocyclic Compounds - chemistry Mass spectrometry Models, Molecular Molecular Conformation NMR spectroscopy Organometallic Compounds - chemistry Polymerization Pyridines - chemistry Stability Stoichiometry Triangles Trimers |
| title | Multicomponent reassembly of terpyridine-based materials: quantitative metallomacrocyclic rearrangement |
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