An Aminopyridinato Titanium Catalyst for the Intramolecular Hydroaminoalkylation of Secondary Aminoalkenes

The easily accessible 2‐(methylamino)pyridinato titanium complex initially synthesized by Kempe is used as catalyst for efficient intramolecular hydroaminoalkylation reactions of secondary aminoalkenes. The corresponding reactions of N‐aryl‐substituted 1‐aminohept‐6‐enes and 1‐aminohex‐5‐enes direct...

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Veröffentlicht in:	Advanced synthesis & catalysis 2015-07, Vol.357 (10), p.2265-2276
Hauptverfasser:	Dörfler, Jaika, Bytyqi, Besnik, Hüller, Sascha, Mann, Nicola M., Brahms, Christian, Schmidtmann, Marc, Doye, Sven
Format:	Artikel
Sprache:	eng
Schlagworte:	Accessibility alkylation amines Catalysis Catalysts CH activation Formations hydroaminoalkylation Synthesis Titanium
Online-Zugang:	Volltext
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