Aerosol flow homogenization in the spray polyphenylene vinylene thin film deposition

Two different spray deposition (SD) techniques – SD and homogenized SD (h-SD), were compared in the case of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylene vinylene] (MDMO-PPV) used as a model material. The h-SD setup includes a homogenizer (a chamber) for homogenization of the spray flow. The...

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Veröffentlicht in:Journal of physics. Conference series 2014-01, Vol.514 (1), p.12006-5
Hauptverfasser: Milenkov, V, Honova, J, Zhivkov, I, Yordanov, R, Vala, M, Mladenova, D, Weiter, M
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container_end_page 5
container_issue 1
container_start_page 12006
container_title Journal of physics. Conference series
container_volume 514
creator Milenkov, V
Honova, J
Zhivkov, I
Yordanov, R
Vala, M
Mladenova, D
Weiter, M
description Two different spray deposition (SD) techniques – SD and homogenized SD (h-SD), were compared in the case of poly[2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylene vinylene] (MDMO-PPV) used as a model material. The h-SD setup includes a homogenizer (a chamber) for homogenization of the spray flow. The homogenizer allows droplet size control and spraying at a low air pressure. Films of about thickness were prepared by SD and h-SD from a toluene solution with a concentration of 0.5 g l−1. Optical micrograph images show that using h-SD results in obtaining uniform films without a distinguishable structure. Imaging by polarized light reveals the typical discs observed often in the spray deposition experiments. The spectral dependence of the photocurrent consists of two peaks. This property makes the structures with h-SD films more attractive for a photovoltaic application since this enhances the photovoltaic conversion in a wider visible light range. The I-V characteristics measured on samples with h-SD films show that exposure to white light increases the current by two orders of magnitude. One can thus conclude that the ITO|MDMO-PPV|Al structures with h-SD MDMO-PPV films behave as a photovoltaic cell.
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subjects Current voltage characteristics
Droplets
Homogenization
Homogenizing
Photoelectric effect
Photomicrographs
Photovoltaic cells
Photovoltaic conversion
Physics
Polarized light
Polyphenylene vinylene
Solar cells
Spray deposition
Sprayers
Spraying
Sprays
Thickness
Thin films
Toluene
White light
title Aerosol flow homogenization in the spray polyphenylene vinylene thin film deposition
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