Characterization of the 1,1-HCl Elimination Reaction of Vibrationally Excited CD3CHFCl Molecules and Assignment of Threshold Energies for 1,1-HCl and 1,2-DCl plus 1,1-HF and 1,2-DF Elimination Reactions

Vibrationally excited CD3CHFCl molecules with 96 kcal mol–1 of energy were generated by the recombination of CD3 and CHFCl radicals in a room-temperature bath gas. The four competing unimolecular decomposition reactions, namely, 1,1-HCl and 1,2-DCl elimination and 1,1-HF and 1,2-DF elimination, were...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2015-09, Vol.119 (36), p.9441-9451
Hauptverfasser:	Brown, Timothy M, Nestler, Matthew J, Rossabi, Samuel M, Heard, George L, Setser, D. W, Holmes, Bert E
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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