Proton-Coupled Electron Transfer in the Reduction of Arenes by SmI2–Water Complexes
The presence of water has a significant impact on the reduction of substrates by SmI2. The reactivity of the Sm(II)-water reducing system and the relationship between sequential or concerted electron-transfer, proton-transfer is not well understood. In this work, we demonstrate that the reduction o...
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Veröffentlicht in: | Journal of the American Chemical Society 2015-09, Vol.137 (35), p.11526-11531 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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