Proton-Coupled Electron Transfer in the Reduction of Arenes by SmI2–Water Complexes

The presence of water has a significant impact on the reduction of substrates by SmI2. The reactivity of the Sm­(II)-water reducing system and the relationship between sequential or concerted electron-transfer, proton-transfer is not well understood. In this work, we demonstrate that the reduction o...

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Veröffentlicht in:Journal of the American Chemical Society 2015-09, Vol.137 (35), p.11526-11531
Hauptverfasser: Chciuk, Tesia V, Flowers, Robert A
Format: Artikel
Sprache:eng
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