Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene
A novel hybrid process for surface fluorination of polymers is being introduced. The process is based on ultra violet (UV) laser radiation, which on the one hand forms radicals out of an atmosphere of a partially fluorinated benzene, and on the other hand activates a polymer surface in the areas whe...
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Veröffentlicht in: | Journal of surface engineered materials and advanced technology 2014-08, Vol.4 (5), p.309-317 |
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creator | Kibben, Simon Vogelsang, Klaus |
description | A novel hybrid process for surface fluorination of polymers is being introduced. The process is based on ultra violet (UV) laser radiation, which on the one hand forms radicals out of an atmosphere of a partially fluorinated benzene, and on the other hand activates a polymer surface in the areas where the UV radiation hits the surface. The radicals can react with the polymer surface, hence altering the surface energy. With this process, a fluorine content of over 30% on the surface of bulk polystyrene can be achieved, while the smallest possible structure size was smaller than 1 mm. |
doi_str_mv | 10.4236/jsemat.2014.45034 |
format | Article |
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With this process, a fluorine content of over 30% on the surface of bulk polystyrene can be achieved, while the smallest possible structure size was smaller than 1 mm.</description><subject>Benzene</subject><subject>Fluorination</subject><subject>Gas phases</subject><subject>Lasers</subject><subject>Polystyrene resins</subject><subject>Radicals</subject><subject>Surface chemistry</subject><subject>Surface energy</subject><issn>2161-4881</issn><issn>2161-489X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNo9kEFLAzEUhIMoWGp_gLccvWzN22STzcGDFluFBXuw4C2k6QtuSTc12Qr9926t-BjezGGYw0fILbCpKLm832bc2X5aMhBTUTEuLsioBAmFqPXH5X-u4ZpMct6y4apKl1qOyMMq9Ml-tzFgTxubMdGn4W_owma6_BwinYdDTG1n-zZ2NHq6jOGY-2PCDm_Ilbch4-TPx2Q1f36fvRTN2-J19tgUDqAWheOaKaGl94prkLYSUq6RlRvHqrVfc1YrVIPkBoE5a8H5GplTnjOlOfd8TO7Ou_sUvw6Ye7Nrs8MQbIfxkA0oppWSNfChCueqSzHnhN7sU7uz6WiAmRMtc6ZlTrTMLy3-A-hjXhE</recordid><startdate>20140801</startdate><enddate>20140801</enddate><creator>Kibben, Simon</creator><creator>Vogelsang, Klaus</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140801</creationdate><title>Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene</title><author>Kibben, Simon ; Vogelsang, Klaus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1184-c3907496ff73916a5466be02dc05bfb3087e77e76de10caa1cf8e0c7f307933f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Benzene</topic><topic>Fluorination</topic><topic>Gas phases</topic><topic>Lasers</topic><topic>Polystyrene resins</topic><topic>Radicals</topic><topic>Surface chemistry</topic><topic>Surface energy</topic><toplevel>online_resources</toplevel><creatorcontrib>Kibben, Simon</creatorcontrib><creatorcontrib>Vogelsang, Klaus</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of surface engineered materials and advanced technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kibben, Simon</au><au>Vogelsang, Klaus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene</atitle><jtitle>Journal of surface engineered materials and advanced technology</jtitle><date>2014-08-01</date><risdate>2014</risdate><volume>4</volume><issue>5</issue><spage>309</spage><epage>317</epage><pages>309-317</pages><issn>2161-4881</issn><eissn>2161-489X</eissn><abstract>A novel hybrid process for surface fluorination of polymers is being introduced. 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source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
subjects | Benzene Fluorination Gas phases Lasers Polystyrene resins Radicals Surface chemistry Surface energy |
title | Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene |
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