Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene

A novel hybrid process for surface fluorination of polymers is being introduced. The process is based on ultra violet (UV) laser radiation, which on the one hand forms radicals out of an atmosphere of a partially fluorinated benzene, and on the other hand activates a polymer surface in the areas whe...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of surface engineered materials and advanced technology 2014-08, Vol.4 (5), p.309-317
Hauptverfasser: Kibben, Simon, Vogelsang, Klaus
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 317
container_issue 5
container_start_page 309
container_title Journal of surface engineered materials and advanced technology
container_volume 4
creator Kibben, Simon
Vogelsang, Klaus
description A novel hybrid process for surface fluorination of polymers is being introduced. The process is based on ultra violet (UV) laser radiation, which on the one hand forms radicals out of an atmosphere of a partially fluorinated benzene, and on the other hand activates a polymer surface in the areas where the UV radiation hits the surface. The radicals can react with the polymer surface, hence altering the surface energy. With this process, a fluorine content of over 30% on the surface of bulk polystyrene can be achieved, while the smallest possible structure size was smaller than 1 mm.
doi_str_mv 10.4236/jsemat.2014.45034
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1709776813</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1709776813</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1184-c3907496ff73916a5466be02dc05bfb3087e77e76de10caa1cf8e0c7f307933f3</originalsourceid><addsrcrecordid>eNo9kEFLAzEUhIMoWGp_gLccvWzN22STzcGDFluFBXuw4C2k6QtuSTc12Qr9926t-BjezGGYw0fILbCpKLm832bc2X5aMhBTUTEuLsioBAmFqPXH5X-u4ZpMct6y4apKl1qOyMMq9Ml-tzFgTxubMdGn4W_owma6_BwinYdDTG1n-zZ2NHq6jOGY-2PCDm_Ilbch4-TPx2Q1f36fvRTN2-J19tgUDqAWheOaKaGl94prkLYSUq6RlRvHqrVfc1YrVIPkBoE5a8H5GplTnjOlOfd8TO7Ou_sUvw6Ye7Nrs8MQbIfxkA0oppWSNfChCueqSzHnhN7sU7uz6WiAmRMtc6ZlTrTMLy3-A-hjXhE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1709776813</pqid></control><display><type>article</type><title>Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><creator>Kibben, Simon ; Vogelsang, Klaus</creator><creatorcontrib>Kibben, Simon ; Vogelsang, Klaus</creatorcontrib><description>A novel hybrid process for surface fluorination of polymers is being introduced. The process is based on ultra violet (UV) laser radiation, which on the one hand forms radicals out of an atmosphere of a partially fluorinated benzene, and on the other hand activates a polymer surface in the areas where the UV radiation hits the surface. The radicals can react with the polymer surface, hence altering the surface energy. With this process, a fluorine content of over 30% on the surface of bulk polystyrene can be achieved, while the smallest possible structure size was smaller than 1 mm.</description><identifier>ISSN: 2161-4881</identifier><identifier>EISSN: 2161-489X</identifier><identifier>DOI: 10.4236/jsemat.2014.45034</identifier><language>eng</language><subject>Benzene ; Fluorination ; Gas phases ; Lasers ; Polystyrene resins ; Radicals ; Surface chemistry ; Surface energy</subject><ispartof>Journal of surface engineered materials and advanced technology, 2014-08, Vol.4 (5), p.309-317</ispartof><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1184-c3907496ff73916a5466be02dc05bfb3087e77e76de10caa1cf8e0c7f307933f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Kibben, Simon</creatorcontrib><creatorcontrib>Vogelsang, Klaus</creatorcontrib><title>Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene</title><title>Journal of surface engineered materials and advanced technology</title><description>A novel hybrid process for surface fluorination of polymers is being introduced. The process is based on ultra violet (UV) laser radiation, which on the one hand forms radicals out of an atmosphere of a partially fluorinated benzene, and on the other hand activates a polymer surface in the areas where the UV radiation hits the surface. The radicals can react with the polymer surface, hence altering the surface energy. With this process, a fluorine content of over 30% on the surface of bulk polystyrene can be achieved, while the smallest possible structure size was smaller than 1 mm.</description><subject>Benzene</subject><subject>Fluorination</subject><subject>Gas phases</subject><subject>Lasers</subject><subject>Polystyrene resins</subject><subject>Radicals</subject><subject>Surface chemistry</subject><subject>Surface energy</subject><issn>2161-4881</issn><issn>2161-489X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNo9kEFLAzEUhIMoWGp_gLccvWzN22STzcGDFluFBXuw4C2k6QtuSTc12Qr9926t-BjezGGYw0fILbCpKLm832bc2X5aMhBTUTEuLsioBAmFqPXH5X-u4ZpMct6y4apKl1qOyMMq9Ml-tzFgTxubMdGn4W_owma6_BwinYdDTG1n-zZ2NHq6jOGY-2PCDm_Ilbch4-TPx2Q1f36fvRTN2-J19tgUDqAWheOaKaGl94prkLYSUq6RlRvHqrVfc1YrVIPkBoE5a8H5GplTnjOlOfd8TO7Ou_sUvw6Ye7Nrs8MQbIfxkA0oppWSNfChCueqSzHnhN7sU7uz6WiAmRMtc6ZlTrTMLy3-A-hjXhE</recordid><startdate>20140801</startdate><enddate>20140801</enddate><creator>Kibben, Simon</creator><creator>Vogelsang, Klaus</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140801</creationdate><title>Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene</title><author>Kibben, Simon ; Vogelsang, Klaus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1184-c3907496ff73916a5466be02dc05bfb3087e77e76de10caa1cf8e0c7f307933f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Benzene</topic><topic>Fluorination</topic><topic>Gas phases</topic><topic>Lasers</topic><topic>Polystyrene resins</topic><topic>Radicals</topic><topic>Surface chemistry</topic><topic>Surface energy</topic><toplevel>online_resources</toplevel><creatorcontrib>Kibben, Simon</creatorcontrib><creatorcontrib>Vogelsang, Klaus</creatorcontrib><collection>CrossRef</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of surface engineered materials and advanced technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kibben, Simon</au><au>Vogelsang, Klaus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene</atitle><jtitle>Journal of surface engineered materials and advanced technology</jtitle><date>2014-08-01</date><risdate>2014</risdate><volume>4</volume><issue>5</issue><spage>309</spage><epage>317</epage><pages>309-317</pages><issn>2161-4881</issn><eissn>2161-489X</eissn><abstract>A novel hybrid process for surface fluorination of polymers is being introduced. The process is based on ultra violet (UV) laser radiation, which on the one hand forms radicals out of an atmosphere of a partially fluorinated benzene, and on the other hand activates a polymer surface in the areas where the UV radiation hits the surface. The radicals can react with the polymer surface, hence altering the surface energy. With this process, a fluorine content of over 30% on the surface of bulk polystyrene can be achieved, while the smallest possible structure size was smaller than 1 mm.</abstract><doi>10.4236/jsemat.2014.45034</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 2161-4881
ispartof Journal of surface engineered materials and advanced technology, 2014-08, Vol.4 (5), p.309-317
issn 2161-4881
2161-489X
language eng
recordid cdi_proquest_miscellaneous_1709776813
source Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals
subjects Benzene
Fluorination
Gas phases
Lasers
Polystyrene resins
Radicals
Surface chemistry
Surface energy
title Ultraviolet Laser Based Gas Phase Fluorination of Polystyrene
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-05T11%3A11%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ultraviolet%20Laser%20Based%20Gas%20Phase%20Fluorination%20of%20Polystyrene&rft.jtitle=Journal%20of%20surface%20engineered%20materials%20and%20advanced%20technology&rft.au=Kibben,%20Simon&rft.date=2014-08-01&rft.volume=4&rft.issue=5&rft.spage=309&rft.epage=317&rft.pages=309-317&rft.issn=2161-4881&rft.eissn=2161-489X&rft_id=info:doi/10.4236/jsemat.2014.45034&rft_dat=%3Cproquest_cross%3E1709776813%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1709776813&rft_id=info:pmid/&rfr_iscdi=true