Increasing robustness against deactivation of nanoporous catalysts by introducing an optimized hierarchical pore network—Application to hydrodemetalation

The macropore network of a hierarchically structured mesoporous hydrodemetalation catalyst is mathematically optimized to maximize the catalytic activity and robustness to deactivation over a given time on stream. A Random Spheres Model (RSM) accounting for catalyst deactivation in both the meso- an...

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Veröffentlicht in:Chemical engineering science 2012-12, Vol.83, p.66-76
Hauptverfasser: Rao, Sanjeev M., Coppens, Marc-Olivier
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Sprache:eng
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